Summary of viscosity ratios comparing ionic liquids (IL), molecular mimics (MM) and molecular mimics under isodensity conditions (MM*).
Setup | Temperature | MM → MM* | MM* → IL | Overall (MM → IL) | References |
---|---|---|---|---|---|
Coarse grained MD simulation | 450 K | — | 75 | — | 47 |
Coarse grained MD simulation after refinement | 350 K | — | 22 | — | 48 |
298 K | — | — | 785a | 48 | |
Coarse grained MD simulation | 370 K | — | 12b | — | 49 |
250 K | — | Approx. 370b | — | 49 | |
Experimental, see Fig. 1 | 295 K | — | — | 30c | 9 |
Experimental | 436 K | 2.4 | 5.1 | 12 | 44 |
387 K | 2.7 | 7.5 | 20 | 44 | |
Experimental | 298 K | 14 | 16 | 219 | This work |
The factor is approximately 550 to 1000 within the viscosity uncertainty.
Obtained via diffusion coefficients, see ESI Section 1.
Likely too low due to additional hydrogen bonding in the molecular mimic.