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. 2022 Feb 7;56(5):3076–3084. doi: 10.1021/acs.est.1c06982

Table 2. Dissolution of Metallic Bismuth in the Absence and Presence of 100 mg L–1 FAa.

  initial conditions
after 2 yrs of storage
sample Bi(0) added (mg) TOC (mg/L) pH Bi (μM) TOC (mg/L) pH Bi(0) dissolved (%) mmol Bi/g C
H2O 47 nd 5.6 0.0 ndc 8.64 <0.01  
H2O 46 nd 5.6 1.1 ndc 8.34 0.01  
FA 44 52.3b 5.49 665 44.3 7.27 6.3 15.0
FA 53 52.3b 5.49 789 43.9 7.23 6.2 18.0
a

The carboxylate group density of the FA was 11.16 mequiv. (g C)−1.24

b

Based on the carbon content given by IHSS.24

c

Not determined.