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. 2021 Feb 12;13(7):8620–8630. doi: 10.1021/acsami.0c18928

Scheme 1. Synthetic Routes for ADI and ADAI.

Scheme 1

(i) (±)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene (BINAP), Pd(dba)2, K2CO3, toluene, reflux (37%); (ii) (±)-BINAP, Pd(OAc)2, tBuOK, 1,4-dioxane, reflux (68%); and (iii) dimethyl sulfoxide (DMSO), tBuOK, hν (ADI: 67%; ADAI: 96%).