. 2021 Feb 12;13(7):8620–8630. doi: 10.1021/acsami.0c18928

Table 1. Optical and Electrochemical Characterization.

	λ_onset^a (nm)	E_opt. (eV)	λ_onset^b (nm)	E_opt. (eV)	E_onset ox. (mV)	HOMO^c (eV)	LUMO^d (eV)
ADI	437	2.83	471	2.63	776	–5.14	–2.31
ADAI	433	2.86	463	2.68	1000	–5.36	–2.50

Spectra acquired in DMF solution.

Spectra for thin films.

E_HOMO = −e(E_onset ox. – E_{onset ox. Fc/Fc⁺}) + E_HOMO Fc (Fc stands for ferrocene; E_{onset ox. Fc/Fc+} = 0.44 V; E_HOMO Fc = −4.8 eV).

E_LUMO = E_HOMO + E_opt.