. 2021 May 10;60(11):7900–7913. doi: 10.1021/acs.inorgchem.1c00410

Table 3. Emission Data of C₂-Symmetrical Complexes (OC-6-33)-[PtCl₂(C^∧N)₂].

C^∧N	medium^a	λ_em (nm)^b	Φ^c	τ (μs)^d	k_r × 10^–3 (s^–1)^e	k_nr × 10^–3 (s^–1)^f
dfppy	CH₂Cl₂	440, 470, 506 (sh)	0.058	44	1.3	21
dfppy	PMMA	439, 469, 500 (sh)	0.21	76.6 (29%), 218 (71%)
ppy^g	CH₂Cl₂	450, 481, 509 (sh)	0.11	27	4.1	33
ppy^g	PMMA	450, 481, 509 (sh)	0.18	57.0 (28%), 157 (72%)
tpy	CH₂Cl₂	457, 489, 524 (sh)	0.15	40	3.8	21
tpy	PMMA	457, 487, 521 (sh)	0.22	84.7 (20%), 208 (80%)
thpy	PMMA	515, 530 (sh), 553	0.054	111	0.5	8.5

Under the exclusion of oxygen.

The most intense peak is italicized.

Quantum yield.

Emission lifetime; relative amplitudes are given in parentheses for biexponential decays.

Radiative rate constant, k_r = Φ/τ.

Nonradiative rate constant, k_nr = (1 – Φ)/τ.

Data in the CH₂Cl₂ solution from ref (21).

Table 3. Emission Data of C2-Symmetrical Complexes (OC-6-33)-[PtCl2(C∧N)2].