Thermal
ellipsoid plot (50% probability) of the cation of 10c·H2O along with the labeling scheme. The
solvent molecule and the hydrogen atoms bonded to carbon have been
omitted for clarity. Selected bond lengths (Å) and angles (deg):
N(1)–C(8) = 1.518(2), C(1)–C(11) = 1.504(3), C(11)–C(14)
= 1.342(3), C(14)–C(15) = 1.532(2), C(15)–C(16) = 1.582(2),
C(16)–C(17) = 1.506(3), C(17)–O(1) = 1.218(2), C(17)–O(2)
= 1.328(2); N(1)–C(8)–C(7) = 104.46(14), C(1)–(11)–C(14)
= 121.73(17), C(11)–C(14)–C(15) = 121.56(17), C(14)–C(15)–C(16)
= 118.26(15), C(15)–C(16)–C(17) = 116.58(15), C(16)–C(17)–O(1)
= 126.22(17), C(16)–C(17)–O(2) = 111.65(16).