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X-ray thermal ellipsoid plot (50% probability) of anti-1a along with the labeling scheme. The hydrogen atoms bonded to carbon have been omitted for clarity. Selected bond lengths (Å) and angles (deg): Pd(1)–Br(1) = 2.4959(3), Pd(1)–N(1) = 2.1124(15), Pd(1)–C(7) = 2.1295(15), Pd(1)–C(8) = 2.1047(15), Pd(1)–C(9) = 2.1181(16), C(7)–C(8) = 1.458(2), C(8)–C(9) = 1.427(2); Br(1)–Pd(1)–N(1) = 92.82(4), C(7)–C(8)–C(9) = 119.41(14), C(8)–C(9)–C(14) = 131.14(14).
