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. 2021 Jan 29;40(4):539–556. doi: 10.1021/acs.organomet.0c00787

Figure 5.

Figure 5

Thermal ellipsoid plot (50% probability) of the cation of one (A) of the two independent molecules of the complex syn-3b·CH2Cl2 showing the labeling scheme. The solvent molecule and the hydrogen atoms bonded to carbon have been omitted for clarity. Selected bond lengths (Å) and angles (deg) are given for both independent molecules (A and A′). For A: Pd(1)–N(1) = 2.131(2), Pd(1)–N(2) = 2.161(2), Pd(1)–C(7) = 2.100(2), Pd(1)–C(8) = 2.138(2), Pd(1)–C(9) = 2.165(2), C(7)–C(8) = 1.454(3), C(8)–C(9) = 1.408(3); N(1)–Pd(1)–N(2) = 90.26(9), C(7)–C(8)–C(9) = 116.9(2), C(8)–C(9)–C(14) = 124.9(2). For A′: Pd(1′)–N(1′) = 2.130(2), Pd(1′)–N(2′) = 2.163(2), Pd(1′)–C(7′) = 2.117(2), Pd(1′)–C(8′) = 2.134(2), Pd(1′)–C(9′) = 2.165(2), C(7′)–C(8′) = 1.452(3), C(8′)–C(9′) = 1.413(3); N(1′)–Pd(1′)–N(2′) = 88.94(8), C(7′)–C(8′)–C(9′) = 117.5(2), C(8)–C(9)–C(14) = 124.0(2).