Thermal ellipsoid plot
(50% probability) of the complex 7c·CHCl3 along with the labeling scheme. The solvent
molecule and the hydrogen atoms bonded to carbon have been omitted
for clarity. Selected bond lengths (Å) and angles (deg): Pd(1)–N(1)
= 2.2185(19), Pd(1)–Cl(1) = 2.3589(5), Pd(1)–C(1) =
2.047(2), Pd(1)–C(3) = 2.159(2), Pd(1)–C(4) = 2.203(2),
Pd(1)–X = 2.065, C(1)–C(2) = 1.553(3), C(2)–C(3)
= 1.542(3), C(3)–C(4) = 1.403(3), C(4)–C(5) = 1.512(3);
N(1)–Pd(1)–Cl(1) = 88.03(5), Cl(1)–Pd(1)–C(1)
= 93.88(6), C(1)–Pd(1)–X = 76.7, X–Pd(1)–N(1)
= 101.3, C(2)–C(3)–C(4) = 117.17(17), C(3)–C(4)–C(5)
= 122.65(18). X represents the midpoint of the double bond C(3)–C(4).