Table 1.
ANOVA table and optimal condition for all target compounds. Values in bold denote statistical significance (p-value < 0.05).
| Compound | Fibre coating (A) |
Extraction mode (B) |
Temperature (C) |
AB |
AC |
BC |
Optimum conditions | ||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| F | P | F | P | F | P | F | P | F | P | F | P | ||
| Fragrance allergens | |||||||||||||
| Pinene | 3.08 | 0.25 | 5.55 | 0.14 | 6.79 | 0.12 | 1.40 | 0.42 | 2.02 | 0.33 | 4.02 | 0.18 | DVB/CAR/PDMS, HS-SPME, 50 °C |
| Limonene | 6.63 | 0.13 | 5.67 | 0.14 | 7.10 | 0.12 | 1.59 | 0.39 | 1.83 | 0.35 | 1.17 | 0.39 | DVB/CAR/PDMS, HS-SPME, 50 °C |
| Benzyl alcohol | 5.82 | 0.15 | 6.33 | 0.13 | 6.35 | 0.13 | 1.65 | 0.38 | 1.86 | 0.35 | 0.48 | 0.56 | DVB/CAR/PDMS, HS-SPME, 50 °C |
| Linalool | 25.1 | 0.04 | 10.1 | 0.09 | 18.0 | 0.05 | 3.76 | 0.21 | 7.39 | 0.12 | 0.62 | 0.51 | DVB/CAR/PDMS, HS-SPME, 50 °C |
| Methyl-2-octynoate | 3.63 | 0.22 | 0.32 | 0.63 | 0.08 | 0.80 | 0.24 | 0.81 | 0.05 | 0.96 | 1.76 | 0.32 | DVB/CAR/PDMS, HS-SPME, 50 °C |
| Citronellol | 3.18 | 0.24 | 0.37 | 0.60 | 0.17 | 0.72 | 0.11 | 0.90 | 0.05 | 0.96 | 2.98 | 0.23 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Citral | 4.97 | 0.17 | 0.13 | 0.76 | 0.25 | 0.65 | 0.31 | 0.76 | 0.13 | 0.88 | 5.04 | 0.15 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Geraniol | 6.42 | 0.15 | 0.01 | 0.94 | 0.00 | 0.99 | 0.96 | 0.51 | 0.10 | 0.90 | 4.28 | 0.17 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Cinnalmaldehyde | 88.1 | 0.01 | 0.03 | 0.88 | 17.1 | 0.05 | 13.2 | 0.07 | 38.8 | 0.03 | 1.51 | 0.34 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Anis alcohol | 4.93 | 0.17 | 12.7 | 0.07 | 0.16 | 0.73 | 3.41 | 0.23 | 0.75 | 0.57 | 0.05 | 0.84 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Cinnamyl alcohol | 5.69 | 0.15 | 7.55 | 0.11 | 0.78 | 0.47 | 9.32 | 0.10 | 0.56 | 0.64 | 1.20 | 0.39 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Eugenol | 571648 | 0.00 | 20182 | 0.00 | 2705 | 0.00 | 22141 | 0.00 | 2662 | 0.00 | 50.4 | 0.02 | PA, HS-SPME, 100 °C |
| Methyleugenol | 11.2 | 0.08 | 0.34 | 0.62 | 8.60 | 0.10 | 3.83 | 0.21 | 0.94 | 0.52 | 16.3 | 0.06 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Isoeugenol | 7.49 | 0.12 | 0.10 | 0.78 | 7.74 | 0.11 | 2.89 | 0.26 | 0.66 | 0.60 | 13.1 | 0.07 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| α-Isomethyl ionone | 8.72 | 0.10 | 7.55 | 0.11 | 9.13 | 0.09 | 2.20 | 0.31 | 1.52 | 0.40 | 5.13 | 0.15 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Lilial | 7.11 | 0.12 | 2.31 | 0.27 | 13.1 | 0.07 | 1.36 | 0.42 | 2.33 | 0.30 | 4.74 | 0.16 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Amylcinnamal | 2.07 | 0.33 | 4.23 | 0.18 | 20.9 | 0.04 | 2.37 | 0.30 | 1.20 | 0.45 | 7.65 | 0.11 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Amylcinnamyl alcohol | 9.33 | 0.10 | 28.7 | 0.03 | 13.7 | 0.07 | 8.94 | 0.10 | 1.19 | 0.46 | 5.00 | 0.15 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Farnesol | 47.2 | 0.02 | 18.2 | 0.05 | 21.3 | 0.04 | 12.3 | 0.08 | 2.90 | 0.26 | 17.2 | 0.05 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Hexylcinnamal | 0.28 | 0.78 | 5.47 | 0.14 | 14.5 | 0.06 | 2.02 | 0.33 | 0.35 | 0.74 | 5.92 | 0.14 | PDMS/DVB, HS-SPME, 100 °C |
| Benzyl benzoate | 6.96 | 0.13 | 19.5 | 0.04 | 21.9 | 0.04 | 1.68 | 0.37 | 2.28 | 0.30 | 17.1 | 0.05 | PDMS/DVB, HS-SPME, 100 °C |
| Benzyl salicylate | 5.16 | 0.16 | 4.30 | 0.17 | 2.43 | 0.26 | 0.90 | 0.52 | 0.20 | 0.83 | 3.52 | 0.20 | PA, HS-SPME, 100 °C |
| Benzyl cinnamate | 11.3 | 0.08 | 91.3 | 0.01 | 8.95 | 0.10 | 5.08 | 0.16 | 0.96 | 0.51 | 0.54 | 0.54 | PA, DI-SPME, 100 °C |
| Synthetic musks | |||||||||||||
| Musk xylene | 13.3 | 0.07 | 1.99 | 0.29 | 57.6 | 0.02 | 3.29 | 0.23 | 4.81 | 0.17 | 16.5 | 0.06 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Musk ambrette | 48.6 | 0.02 | 13.9 | 0.07 | 104 | 0.01 | 14.0 | 0.07 | 13.8 | 0.07 | 26.5 | 0.04 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| Musk moskene | 9.20 | 0.10 | 7.09 | 0.12 | 58.4 | 0.02 | 3.36 | 0.23 | 3.98 | 0.20 | 22.2 | 0.04 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Musk tibetene | 6.35 | 0.14 | 2.19 | 0.28 | 80.6 | 0.01 | 4.36 | 0.19 | 2.63 | 0.28 | 23.6 | 0.04 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Galaxolide | 3.78 | 0.21 | 5.37 | 0.15 | 23.6 | 0.04 | 1.87 | 0.35 | 1.27 | 0.44 | 4.61 | 0.16 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Celestolide | 5.35 | 0.16 | 10.9 | 0.08 | 18.8 | 0.04 | 2.02 | 0.33 | 1.56 | 0.39 | 6.77 | 0.12 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Phantolide | 7.40 | 0.12 | 11.0 | 0.08 | 34.2 | 0.03 | 2.16 | 0.32 | 2.66 | 0.27 | 11.8 | 0.08 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Cashmeran | 8.83 | 0.10 | 3.06 | 0.22 | 8.61 | 0.10 | 1.29 | 0.44 | 1.39 | 0.42 | 6.15 | 0.13 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Traseolide | 3.01 | 0.25 | 14.1 | 0.06 | 25.6 | 0.04 | 1.81 | 0.36 | 1.13 | 0.47 | 9.14 | 0.09 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Tonalide | 4.59 | 0.18 | 12.4 | 0.07 | 40.0 | 0.02 | 2.14 | 0.32 | 1.97 | 0.34 | 14.2 | 0.06 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Ambrettolide | 0.35 | 0.74 | 11.1 | 0.08 | 13.8 | 0.07 | 1.85 | 0.35 | 0.25 | 0.80 | 5.06 | 0.15 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| Preservatives | |||||||||||||
| PhEtOH | 13.6 | 0.07 | 2.56 | 0.25 | 0.25 | 0.67 | 3.86 | 0.21 | 3.43 | 0.23 | 1.55 | 0.34 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| BHA | 6.69 | 0.13 | 19.3 | 0.04 | 0.12 | 0.76 | 3.48 | 0.22 | 0.23 | 0.81 | 19.7 | 0.04 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| BHT | 11.2 | 0.08 | 29.2 | 0.03 | 2.99 | 0.23 | 6.88 | 0.13 | 0.89 | 0.53 | 2.86 | 0.23 | DVB/CAR/PDMS, HS-SPME, 100 °C |
| TCS | 8470 | 0.00 | 138966 | 0.00 | 14456 | 0.00 | 2771 | 0.00 | 880 | 0.00 | 5719 | 0.00 | PA, DI-SPME, 100 °C |
| MeP | 92.9 | 0.01 | 29.6 | 0.03 | 11.5 | 0.07 | 23.8 | 0.04 | 0.12 | 0.89 | 18.1 | 0.05 | PA, HS-SPME, 100 °C |
| EtP | 13.2 | 0.07 | 8.21 | 0.10 | 5.49 | 0.14 | 4.30 | 0.19 | 0.46 | 0.68 | 8.77 | 0.10 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| iPrP | 2.12 | 0.32 | 16.7 | 0.06 | 1.17 | 0.39 | 0.96 | 0.51 | 1.61 | 0.38 | 3.06 | 0.22 | DVB/CAR/PDMS, DI-SPME, 50 °C |
| iBuP | 79.0 | 0.01 | 140 | 0.01 | 14.1 | 0.06 | 43.1 | 0.02 | 1.65 | 0.38 | 22.4 | 0.04 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| BzP | 2.44 | 0.29 | 16.7 | 0.05 | 0.42 | 0.58 | 1.39 | 0.42 | 0.15 | 0.87 | 4.59 | 0.17 | PA, DI-SPME, 100 °C |
| Plasticizers | |||||||||||||
| DMP | 0.84 | 0.54 | 1.07 | 0.41 | 1.59 | 0.33 | 0.79 | 0.56 | 0.87 | 0.54 | 1.42 | 0.36 | PDMS/DVB, HS-SPME, 100 °C |
| DEP | 18.8 | 0.05 | 31.8 | 0.03 | 7.72 | 0.11 | 5.03 | 0.17 | 0.17 | 0.85 | 15.7 | 0.06 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| DIBP | 13.8 | 0.07 | 4.71 | 0.16 | 30.0 | 0.03 | 4.84 | 0.17 | 5.82 | 0.15 | 3.43 | 0.21 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| DBP | 3.20 | 0.24 | 20.2 | 0.04 | 20.7 | 0.04 | 3.70 | 0.21 | 0.93 | 0.52 | 1.11 | 0.40 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| DIPP | 0.09 | 0.92 | 0.33 | 0.62 | 21.8 | 0.04 | 1.45 | 0.41 | 0.03 | 0.97 | 3.17 | 0.22 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| DPP | 0.34 | 0.75 | 1.59 | 0.33 | 17.1 | 0.05 | 1.06 | 0.49 | 0.03 | 0.98 | 1.71 | 0.32 | PA, DI-SPME, 100 °C |
| BBP | 101 | 0.01 | 1411 | 0.00 | 209 | 0.00 | 50.7 | 0.02 | 4.44 | 0.14 | 55.6 | 0.02 | PA, DI-SPME, 100 °C |
| DIHP | 2.52 | 0.28 | 0.98 | 0.43 | 11.2 | 0.08 | 0.64 | 0.61 | 1.58 | 0.39 | 3.31 | 0.21 | PA, HS-SPME, 100 °C |
| DEHP | 4.01 | 0.20 | 1.56 | 0.34 | 13.6 | 0.07 | 0.83 | 0.55 | 2.89 | 0.26 | 2.58 | 0.25 | PA, HS-SPME, 100 °C |
| DCHP | 56.1 | 0.02 | 414 | 0.00 | 79.3 | 0.01 | 32.8 | 0.03 | 5.48 | 0.15 | 27.8 | 0.03 | PA, DI-SPME, 100 °C |
| DPhP | 1022 | 0.00 | 9456 | 0.00 | 142 | 0.01 | 1003 | 0.00 | 3.49 | 0.22 | 138 | 0.01 | PA, DI-SPME, 100 °C |
| DNOP | 36.5 | 0.03 | 0.06 | 0.83 | 75.8 | 0.01 | 0.53 | 0.65 | 31.2 | 0.03 | 0.71 | 0.49 | PA, HS-SPME, 100 °C |
| DMA | 57.6 | 0.02 | 2.89 | 0.23 | 11.4 | 0.08 | 0.73 | 0.58 | 3.00 | 0.25 | 2.63 | 0.25 | DVB/CAR/PDMS, HS-SPME, 50 °C |
| DEA | 5.87 | 0.15 | 1.52 | 0.34 | 0.72 | 0.48 | 1.06 | 0.49 | 0.13 | 0.88 | 5.17 | 0.15 | DVB/CAR/PDMS, DI-SPME, 100 °C |
| DEHA | 1.05 | 0.49 | 2.63 | 0.25 | 9.43 | 0.09 | 0.99 | 0.50 | 0.75 | 0.57 | 3.32 | 0.21 | PA, HS-SPME, 100 °C |