Table 3.
Concentration (μg g−1) of the target compounds in the analyzed real hydroalcoholic gel samples.
| Compounds | G1 | G2 | G3 | G4 | G5 | G6 | G7 | G8 | G9 | G10 |
|---|---|---|---|---|---|---|---|---|---|---|
| Fragrance allergens | ||||||||||
| Pinene | 0.0220 ± 0.0014 | 0.899 ± 0.014 | 0.195 ± 0.013 | 0.048 ± 0.014 | 1.04 ± 0.25 | |||||
| Limonene | 1.29 ± 0.10 | 0.117 ± 0.010 | 3.07 ± 0.73 | 6.80 ± 0.54 | 0.665 ± 0.037 | 12.4 ± 1.2 | 4.4 ± 1.7 | 29.2 ± 9.0 | 0.77 ± 0.10 | |
| Benzyl Alcohol | 2.36 ± 0.23 | 0.1714 ± 0.0027 | 10.23 ± 0.87 | 0.671 ± 0.010 | 11.76 ± 0.78 | 4.5 ± 1.6 | 28.2 ± 7.0 | 0.93 ± 0.10 | ||
| Linalool | 0.182 ± 0.068 | 143.9 ± 5.2 | 1.669 ± 0.011 | 15.5 ± 1.4 | 1.459 ± 0.016 | 1.750 ± 0.084 | 15 ± 4 | 36.23 ± 0.40 | ||
| Methyl-2-octynoate | 0.148 ± 0.053 | 0.279 ± 0.043 | 0.414 ± 0.019 | 2.19 ± 0.57 | 0.650 ± 0.011 | 2.581 ± 0.026 | 1.378 ± 0.010 | 4.1 ± 1.2 | 2.967 ± 0.047 | |
| Citronellol | 2.28 ± 0.61 | 0.1796 ± 0.0011 | 0.122 ± 0.029 | 53.5 ± 2.6 | 7.62 ± 0.96 | 6.85 ± 0.13 | 29.9 ± 0.50 | |||
| Citral | 0.45 ± 0.13 | 2.79 ± 0.43 | 0.210 ± 0.010 | 98.7 ± 2.0 | 36.3 ± 4.1 | 3.85 ± 0.41 | 25.9 ± 7.3 | 2.94 ± 0.11 | ||
| Geraniol | 6.7 ± 1.5 | 3.24 ± 0.37 | 172 ± 12 | 41.6 ± 4.6 | 3.67 ± 0.27 | 217 ± 44 | 26.7 ± 1.2 | |||
| Cinnamaldehyde | 59 ± 14 | 0.2271 ± 0.0012 | 0.173 ± 0.021 | 0.140 ± 0.011 | 5.56 ± 0.50 | |||||
| Anis alcohol | 11 ± 1.0 | |||||||||
| Cinnamyl alcohol | 71 ± 21 | 0.99 ± 0.33 | 159 ± 14 | 2.55 ± 0.12 | ||||||
| Eugenol | 26.0 ± 3.2 | 0.194 ± 0.021 | 5.8 ± 1.7 | 0.634 ± 0.084 | ||||||
| Methyleugenol | 4.73 ± 0.51 | |||||||||
| Isoeugenol | 2.16 ± 0.49 | 2.347 ± 0.050 | 1.172 ± 0.041 | 3.56 ± 0.82 | 1.437 ± 0.086 | |||||
| α-isomethylionone | 2.46 ± 0.59 | 0.027 ± 0.010 | 0.441 ± 0.070 | 0.89 ± 0.10 | 0.0453 ± 0.0041 | 2.24 ± 0.28 | 1.74 ± 0.31 | 9.957 ± 0.048 | ||
| Lilial® | 0.166 ± 0.049 | 0.0109 ± 0.0012 | 0.458 ± 0.020 | 4.910 ± 0.026 | 6.05 ± 0.37 | 7.123 ± 0.016 | ||||
| Amylcinnamyl alcohol | 0.89 ± 0.27 | 11.4 ± 1.0 | 0.539 ± 0.095 | |||||||
| Farnesol | 8.9 ± 2.4 | 0.0613 ± 0.0081 | 2.782 ± 0.023 | 10.85 ± 0.34 | ||||||
| Hexylcinnamal | 0.125 ± 0.010 | 1.15 ± 0.11 | 1.034 ± 0.092 | |||||||
| Benzyl benzoate | 17.8 ± 5.4 | 0.45 ± 0.11 | 0.308 ± 0.016 | 0.75 ± 0.22 | 0.194 ± 0.010 | 0.233 ± 0.039 | 0.685 ± 0.054 | 22.0 ± 5.3 | 9.91 ± 0.51 | |
| Benzyl salicylate | 0.91 ± 0.25 | 0.044 ± 0.010 | 0.0346 ± 0.0028 | 0.0773 ± 0.0017 | 4.0 ± 1.0 | 5.04 ± 0.88 | ||||
| Benzyl cinnamate | 0.33 ± 0.10 | 0.0201 ± 0.0034 | 0.0192 ± 0.0013 | |||||||
| Synthetic musks | ||||||||||
| Galaxolide | 16.0 ± 4.4 | 0.380 ± 0.060 | 0.129 ± 0.016 | 0.137 ± 0.011 | 32.8 ± 4.1 | 32.4 ± 5.2 | ||||
| Cashmeran | 0.164 ± 0.010 | 0.254 ± 0.055 | 19.1 ± 2.8 | 0.561 ± 0.070 | 0.173 ± 0.020 | 0.131 ± 0.026 | 0.230 ± 0.028 | |||
| Traseolide | 1.82 ± 0.38 | |||||||||
| Ambrettolide | 4.0 ± 1.0 | |||||||||
| Preservatives | ||||||||||
| PhEtOH | 72.49 ± 0.48 | |||||||||
| BHT | 0.298 ± 0.010 | 0.0121 ± 0.0014 | 0.0099 ± 0.0010 | 0.052 ± 0.010 | ||||||
| TCS | 0.32 ± 0.10 | |||||||||
| MeP | 23 ± 3.6 | 2.58 ± 0.27 | 2.54 ± 0.82 | 1.194 ± 0.011 | ||||||
| EtP | 50 ± 11 | 29.6 ± 3.6 | 7.26 ± 0.90 | 1.06 ± 0.10 | 1.81 ± 0.18 | 2.36 ± 0.45 | ||||
| PrP | 3.921 ± 0.024 | 150 ± 13 | ||||||||
| iBuP | 1.23 ± 0.34 | 61.2 ± 1.8 | ||||||||
| Plasticizers | ||||||||||
| DMP | 0.428 ± 0.056 | 0.590 ± 0.010 | 9.6 ± 1.9 | |||||||
| DEP | 1.709 ± 0.075 | 0.2305 ± 0.0034 | 25.48 ± 0.90 | 3.25 ± 0.23 | 0.191 ± 0.025 | 104.2 ± 6.9 | 1.87 ± 0.21 | |||
| DEHP | 0.43 ± 0.13 | 0.128 ± 0.034 | 0.155 ± 0.021 | 0.1145 ± 0.0041 | ||||||
| DMA | 0.221 ± 0.010 | 0.107 ± 0.010 | 0.228 ± 0.040 | 4.07 ± 0.13 | ||||||
| DEA | 1.08 ± 0.32 | |||||||||