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. Author manuscript; available in PMC: 2023 Jan 18.
Published in final edited form as: Environ Sci Technol. 2022 Jan 5;56(2):1162–1173. doi: 10.1021/acs.est.1c06990

Table 1.

Concentrations of FTOH and 6:2 FTEOs in Anti-fog Sprays and Clothsa

Concentration (μg/mL) Concentration (μg/g)


Spray A Spray B Spray C Spray D Cloth A Cloth B Cloth C Cloth D Cloth E
6:2FTOH 10,600 25.8 3.46 3.43 1.29 3.95 38.4 7.94 9.62
8:2FTOH - - - - 127 - - - -
10:2FTOH - - - - 15.5 - - - -
6:2FTEO1b N.Q. N.Q. N.Q. N.Q. N.Q. N.Q. N.Q. N.Q. N.Q.
6:2FTEO2 35.2 1.08 0.193 0.194 1.29 53.3 126 208 244
6:2FTEO3 129 2.55 0.8 0.804 3.64 260 566 746 726
6:2FTEO4 1010 16.2 8.84 8.89 28.9 2770 6140 7340 5780
6:2FTEO5 2670 42.8 33 32.1 99 9420 22,100 23,400 17,200
6:2FTEO6 2790 50.1 52.9 51.4 134 12,200 29,200 33,200 21,300
6:2FTEO7 2200 46.8 64.6 63 125 12,200 29,300 30,400 20,800
6:2FTEO8 1720 44.3 73.4 75.9 104 10,600 26,300 28,400 18,900
6:2FTEO9 1280 35.4 76 78.3 77.9 7540 21,900 21,500 15,800
6:2FTEO10 964 28 77.6 79.7 57.2 5380 16,500 17,000 11,800
6:2FTEO11 616 17.2 67.3 66 35.7 3280 11,100 10,900 7830
6:2FTEO12 429 9.53 39.8 49.2 25 1720 6800 6230 4450
6:2FTEO13 517 7.19 31.1 57.1 7.34 1680 6090 5930 3120
Σionic PFASc 1.37 0.062 0.019 0.037 2.09 0.156 1.51 2.68 0.825
ΣPFAS 25,000 327 529 566 702 67,100 176,000 185,000 128,000
TOF measurement 20,700
(508)
221 (3) 202 (2) 190 (1) 46,800
(5200)
44,200
(2200)
131,500
(2200)
92,000
(2700)
73,900
(2900)
% TOF explained by FTEOs and FTOHs 60% 57% 88% 99% 1% 55% 48% 72% 62%
a

TOF measurements are reported as the average of triplicate analysis, with standard deviations in parenthesis.

b

6:2FTEO1 was unable to be quantified via HPLC–HRMS methods as the other FTEOs were and is denoted as N.Q.

c

See Table S3 for the list of ionic PFAS quantified.