Table 1.
Content (%) C | ||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
No. | Compounds | LRIexp A | LRIlit B | C1 | C2 | C3 | C4 | C5 | C6 | C7 | Ident. D | Sign. E |
1 | α-Pinene | 936 | 934 | 2.98 a | 2.57 c | - | 2.69 b | 1.67 d | 3.01 a | 1.49 e | 1, 2, 3 | ** |
2 | β-Pinene | 977 | 981 | 3.33 a | - | 0.91 d | 2.71 b | - | 2.73 b | 1.58 c | 1, 2, 3 | ** |
3 | β-Myrcene | 990 | 994 | 2.76 d | 7.52 a | 1.95 f | 2.04 e | 5.61 b | 1.00 | 4.13 c | 1, 2, 3 | ** |
4 | n-Octanal | 1001 | 1005 | 3.77 a | - | - | 1.35 b | - | - | - | 1, 2 | ** |
5 | d-limonene | 1031 | 1028 | 77.53 d | 80.50 c | 33.35 f | 76.00 e | 82.78 b | 76.06 e | 89.17 a | 1, 2, 3 | ** |
6 | β-cis-Ocimene | 1038 | 1036 | - | 1.45 a | - | 0.92 d | - | 1.18 c | 1.04 b | 1, 2 | ** |
7 | n-Octanol | 1070 | 1078 | - | - | 1.59 a | - | - | - | - | 1, 2, 3 | ** |
8 | β-Linalool | 1098 | 1101 | 2.58 c | 1.04 f | 7.69 a | 2.67 b | 1.89 e | 2.31 d | 1.03 f | 1, 2 | ** |
9 | α-Terpineol | 1189 | 1194 | - | - | 7.06 a | 1.08 c | 0.91 d | 1.17 b | - | 1, 2 | ** |
10 | n-Decanal | 1203 | 1208 | 2.07 a | - | - | - | - | - | - | 1, 2 | ** |
11 | cis-Geraniol | 1229 | 1235 | - | - | 1.63 a | - | - | - | - | 1, 2 | ** |
12 | β-Citral | 1238 | 1242 | - | - | 1.88 a | - | - | - | - | 1, 2 | ** |
13 | Bergamol | 1256 | 1258 | - | 1.46 d | 6.77 a | 3.55 c | 1.43 d | 4.33 b | - | 1, 2 | ** |
14 | trans-Geraniol | 1259 | 1267 | - | - | 3.36 a | - | - | - | - | 1, 2 | ** |
15 | Neryl Acetate | 1365 | 1366 | - | - | 6.28 a | - | - | - | - | 1, 2 | ** |
16 | Geranyl Acetate | 1386 | 1392 | - | - | 10.12 a | 1.41 c | - | 1.51 d | - | 1, 2 | ** |
17 | n-Decyl Acetate | 1402 | 1406 | - | - | 1.44 a | - | - | - | - | 1, 2 | ** |
18 | Caryophyllene | 1419 | 1423 | - | - | 1.00 a | - | - | - | - | 1, 2, 3 | ** |
19 | Germacrene D | 1480 | 1485 | - | - | 3.48 a | - | - | - | - | 1, 2 | ** |
20 | trans-Nerolidol | 1550 | 1554 | - | - | 4.57 a | - | - | - | - | 1, 2 | ** |
Monoterpene Hydrocarbons | 86.60 | 92.04 | 36.21 | 84.36 | 90.06 | 84.52 | 97.41 | |||||
Oxygenated Monoterpenes | 2.58 | 2.50 | 44.79 | 8.71 | 4.23 | 9.32 | 1.03 | |||||
Sesquiterpene Hydrocarbons | - | - | 4.48 | - | - | - | - | |||||
Oxygenated Sesquiterpenes | - | - | 4.57 | - | - | - | - | |||||
Others | 5.84 | - | 3.03 | 1.35 | - | - | - | |||||
Total | 95.02 | 94.54 | 93.08 | 94.42 | 94.29 | 93.84 | 98.44 |
A Linear retention index, obtained through the modulated chromatogram, reported for DB-5MS apolar column; B linear retention index reported for DB-5MS column or equivalents reported in the literature; C content is the peak volume percentage of compounds in the essential oil sample; D 1 = retention index identical to bibliography; 2 = identification based on comparison of MS; 3 = retention time identical to authentic compounds. Compounds are classified in order of linear retention time of non-polar column. E Sign: significance at p < 0.05. Results followed by different letters in the same line are significantly different (p < 0.05) according to Tukey’s multiple range test.