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. 2022 Feb 27;27(5):1580. doi: 10.3390/molecules27051580

Table 1.

Composition (%) of the essential oils of the seven C. aurantium cultivars collected in the Botanical Garden of Palermo, Sicily.

Content (%) C
No. Compounds LRIexp A LRIlit B C1 C2 C3 C4 C5 C6 C7 Ident. D Sign. E
1 α-Pinene 936 934 2.98 a 2.57 c - 2.69 b 1.67 d 3.01 a 1.49 e 1, 2, 3 **
2 β-Pinene 977 981 3.33 a - 0.91 d 2.71 b - 2.73 b 1.58 c 1, 2, 3 **
3 β-Myrcene 990 994 2.76 d 7.52 a 1.95 f 2.04 e 5.61 b 1.00 4.13 c 1, 2, 3 **
4 n-Octanal 1001 1005 3.77 a - - 1.35 b - - - 1, 2 **
5 d-limonene 1031 1028 77.53 d 80.50 c 33.35 f 76.00 e 82.78 b 76.06 e 89.17 a 1, 2, 3 **
6 β-cis-Ocimene 1038 1036 - 1.45 a - 0.92 d - 1.18 c 1.04 b 1, 2 **
7 n-Octanol 1070 1078 - - 1.59 a - - - - 1, 2, 3 **
8 β-Linalool 1098 1101 2.58 c 1.04 f 7.69 a 2.67 b 1.89 e 2.31 d 1.03 f 1, 2 **
9 α-Terpineol 1189 1194 - - 7.06 a 1.08 c 0.91 d 1.17 b - 1, 2 **
10 n-Decanal 1203 1208 2.07 a - - - - - - 1, 2 **
11 cis-Geraniol 1229 1235 - - 1.63 a - - - - 1, 2 **
12 β-Citral 1238 1242 - - 1.88 a - - - - 1, 2 **
13 Bergamol 1256 1258 - 1.46 d 6.77 a 3.55 c 1.43 d 4.33 b - 1, 2 **
14 trans-Geraniol 1259 1267 - - 3.36 a - - - - 1, 2 **
15 Neryl Acetate 1365 1366 - - 6.28 a - - - - 1, 2 **
16 Geranyl Acetate 1386 1392 - - 10.12 a 1.41 c - 1.51 d - 1, 2 **
17 n-Decyl Acetate 1402 1406 - - 1.44 a - - - - 1, 2 **
18 Caryophyllene 1419 1423 - - 1.00 a - - - - 1, 2, 3 **
19 Germacrene D 1480 1485 - - 3.48 a - - - - 1, 2 **
20 trans-Nerolidol 1550 1554 - - 4.57 a - - - - 1, 2 **
Monoterpene Hydrocarbons 86.60 92.04 36.21 84.36 90.06 84.52 97.41
Oxygenated Monoterpenes 2.58 2.50 44.79 8.71 4.23 9.32 1.03
Sesquiterpene Hydrocarbons - - 4.48 - - - -
Oxygenated Sesquiterpenes - - 4.57 - - - -
Others 5.84 - 3.03 1.35 - - -
Total 95.02 94.54 93.08 94.42 94.29 93.84 98.44

A Linear retention index, obtained through the modulated chromatogram, reported for DB-5MS apolar column; B linear retention index reported for DB-5MS column or equivalents reported in the literature; C content is the peak volume percentage of compounds in the essential oil sample; D 1 = retention index identical to bibliography; 2 = identification based on comparison of MS; 3 = retention time identical to authentic compounds. Compounds are classified in order of linear retention time of non-polar column. E Sign: significance at p < 0.05. Results followed by different letters in the same line are significantly different (p < 0.05) according to Tukey’s multiple range test.