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. 2022 Feb 28;27(5):1616. doi: 10.3390/molecules27051616

Table 10.

Selected characterization data for the polymers prepared by the pre- and [post-] functionalization methods developed by Houck et al. [75].

Polymer Mw1 (kDa) Ɖ 4 Tg2 (°C) Td3 (°C) Char Yield 4 (%)
poly36 332.7 2.5 6 127 8
poly36a 73.7 [128.9] 1.9 [1.4] 62 192 33
poly36b 112.1 [275.1] 2.1 [2.0] 62 247 28
poly36c [228.1] 2.8 153 40
poly36d 32.1 [171.7] 2.1 [2.6] 138 312 9
poly36e [54.9] [2.2] 77 265 50
poly36f [22.9] [2.1] 181 (405) 5 45 (67) 5
poly36g 142.4 3.5 85 250 38
poly36h [172.3] [2.8] 81 293 29
poly37 217.0 2.1 227 229 30
poly37a 55.4 [28.2] 1.9 [2.0] 186 392 29
poly37b 192.7 [55.5] 2.0 [1.8] 175 385 35
poly37c 2.3 2.8 100 376 58
poly37d 69.9 1.9 190 368 26
poly37e 127.0 3.2 233 52
Poly37f [73.3] [1.8] 62 (355) 5 49 (60) 5

1 Determined by GPC in THF against PS standards. 2 DSC in nitrogen with heating at 5 °C/min, determined on the third heating cycle. 3 TGA onset in nitrogen with heating at 10 °C/min. 4 TGA at 900 °C in nitrogen. 5 Values observed as the second scan after cure by DSC.