Table 10.
Polymer | Mw1 (kDa) | Ɖ 4 | Tg2 (°C) | Td3 (°C) | Char Yield 4 (%) |
---|---|---|---|---|---|
poly36 | 332.7 | 2.5 | 6 | 127 | 8 |
poly36a | 73.7 [128.9] | 1.9 [1.4] | 62 | 192 | 33 |
poly36b | 112.1 [275.1] | 2.1 [2.0] | 62 | 247 | 28 |
poly36c | [228.1] | 2.8 | 153 | 40 | |
poly36d | 32.1 [171.7] | 2.1 [2.6] | 138 | 312 | 9 |
poly36e | [54.9] | [2.2] | 77 | 265 | 50 |
poly36f | [22.9] | [2.1] | 181 (405) 5 | 45 (67) 5 | |
poly36g | 142.4 | 3.5 | 85 | 250 | 38 |
poly36h | [172.3] | [2.8] | 81 | 293 | 29 |
poly37 | 217.0 | 2.1 | 227 | 229 | 30 |
poly37a | 55.4 [28.2] | 1.9 [2.0] | 186 | 392 | 29 |
poly37b | 192.7 [55.5] | 2.0 [1.8] | 175 | 385 | 35 |
poly37c | 2.3 | 2.8 | 100 | 376 | 58 |
poly37d | 69.9 | 1.9 | 190 | 368 | 26 |
poly37e | 127.0 | 3.2 | 233 | 52 | |
Poly37f | [73.3] | [1.8] | 62 (355) 5 | 49 (60) 5 |
1 Determined by GPC in THF against PS standards. 2 DSC in nitrogen with heating at 5 °C/min, determined on the third heating cycle. 3 TGA onset in nitrogen with heating at 10 °C/min. 4 TGA at 900 °C in nitrogen. 5 Values observed as the second scan after cure by DSC.