Scheme 8.
Synthesis of resolvin D2, as reported by Rizzacasa et al. [86]. Reagents and conditions: i. Ph3PdCl2, CuI, Et3N, 0 °C to rt, 83%; ii. MeOH, HCl, rt, 85%; iii. Zn (Cu/Ag), MeOH, H2O, 76%; iv. LiOH, 1M, THF, 0 °C, 81%.
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