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. Author manuscript; available in PMC: 2022 Jun 16.
Published in final edited form as: J Am Chem Soc. 2021 Jun 2;143(23):8597–8602. doi: 10.1021/jacs.1c03718

Table 3.

Electrophotocatalytic Ritter-type C–H amination of complex molecules.a

graphic file with name nihms-1785324-t0004.jpg
a

Reaction conditions: substrate (0.3–0.5 mmol, 1.0 equiv), H2O (1.0 equiv), 1 (8 mol %), nBu4NPF6 (1.0 equiv), TFA (0.2 mL), MeCN (6.0 mL) [anode], and nBu4NPF6 (1.0 equiv), TFA (0.2 mL), MeCN (6.0 mL) [cathode] in H-type divided cell with carbon felt anode, Pt cathode. Reactions performed under constant voltage (CV) conditions with light irradiation for 48 h at rt under N2, isolated yield.

b

LiClO4 instead of nBu4NPF6.

c

72 h reaction time.

d

Run at 2.6 V.