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. 2022 Jan 18;18(2):155–158. doi: 10.1007/s13181-022-00876-5

Table 2.

Differential diagnosis according to arterial pH, anion gap, osmol gap, and ketone bodies. For contribution to osmol gap, toxin concentration is expressed in mg/dL. The values of anion and osmol gap are influenced by the delay from exposure. *Estimation of contribution of propylene glycol (PG) concentration to osmol gap in patients receiving lorazepam infusions: [PG] mg/dL = 14.22 + 1.94*osmol gap [Ref 2]. (

Adapted from https://www.healthcare.uiowa.edu/path_handbook/Appendix/Chem/OSMO_GAP.html, accessed Dec 12, 2021)

Arterial pH Anion gap Ketone Osmol gap Contribution to osmol gap
Ethanol Nl Nl Nl [Ethanol]/3.8
Methanol Nl ↑ or Nl [Methanol]/3.2
Ethylene glycol Nl ↑ or Nl [Ethylene glycol]/6.2
Isopropanol Nl Nl [Isopropanol]/6.0
Propylene glycol Nl ↑ or Nl [Propylene glycol]/2.8*
Alcoholic ketoacidosis Contribution of acetone debated [3]