(A) [13]-13C-glucose becomes [2,3]-13C pyruvate if it is directly metabolized through the glycolytic pathway. [2,3]-13C-pyruvate can enter the TCA cycle through pyruvate dehydrogenase (PDH) or pyruvate carboxylase (PC). Blue dots indicate 13C carbons from glucose entering TCA cycle via PDH. Red dots indicate 13C carbons from glucose entering TCA cycle via PC. (B) Representative spectra of the glutamate C2-C4 fragments from TIGAR knockout SH-SY5Y cells labeled with d-glucose-[1,2]-13
C2. M0 of the C2-C4 glutamate fragment is m/z 128, m1 of glutamate is m/z 129 (blue) that indicates the presence of 13C at the fourth carbon position, and m2 glutamate indicates the presence of 13C at the second and third carbon positions (red). (C) The cellular acetyl-CoA and (D) acetyl-carnitine levels in SH-SY5Y cell pellets were measured as described in ‘Method details,’ and the data are presented as the mean ± SD. (E) Seahorse flux analyses of oxygen consumption rate (OCR) were performed as described in ‘Method details,’ and the data are presented as the mean ± SEM. Statistical analyses are described in ‘Method details.’ *p<0.05, **p<0.01, ***p<0.001, ****p<0.0001.
Figure 6—figure supplement 1—source data 1. Raw metabolites data including cellular acetyl-CoA and acetyl-carnitine were collected from SH-SY5Y control and whole-body Tigar knockout (TKO) cell pellet as described in ‘Method details’.