Table 2.
Kinetic parameters for DC adsorption on AC and MAC.
Kinetic model | Parameters | Adsorbents and initial concentrations | |||
---|---|---|---|---|---|
AC 100 mg/L | MAC 100 mg/L | AC 50 mg/L | MAC 50 mg/L | ||
Pseudo-first-order | |||||
K 1 (1/min) | 0.0361 | 0.0332 | 0.0341 | 0.0373 | |
q e (mg/g) | 43.39 | 41.07 | 21.96 | 21.82 | |
R 2 | 0.979 | 0.982 | 0.989 | 0.987 | |
| |||||
Pseudo-second-order | |||||
K 2 (1/min) | 9.7 × 10−4 | 6.6 × 10−4 | 2.1 × 10−3 | 1.4 × 10−3 | |
q e (mg/g) | 43.10 | 40.98 | 23.75 | 21.28 | |
R 2 | 0.994 | 0.983 | 0.996 | 0.987 | |
| |||||
Power function | |||||
α | 4.14 | 2.32 | 3.45 | 1.01 | |
b | 0.48 | 0.55 | 0.38 | 0.99 | |
R 2 | 0.97 | 0.89 | 0.91 | 1.00 | |
| |||||
Natarajan and Khalaf | |||||
K N (1/min) | 0.0060 | 0.0040 | 0.0070 | 0.0050 | |
R 2 | 0.725 | 0.720 | 0.750 | 0.720 | |
| |||||
Intraparticle diffusion | |||||
K diff (mg/g min1/2) | 2.34 | 2.36 | 1.24 | 1.21 | |
C | 9.06 | 4.22 | 6.12 | 2.95 | |
R 2 | 0.816 | 0.822 | 0.806 | 0.807 |