Table 2.
Selected bond lengths (Å) and angles (o) for complexes 1 and 2.
| Complex 1 | Complex 2 | ||
|---|---|---|---|
| Zn(1)-O(5) | 2.1361(11) | Fe(1)-O(5) | 2.1031(11) |
| Zn(1)-O(5)#1 | 2.1361(11) | Fe(1)-O(5)#1 | 2.1032(11) |
| Zn(1)-N(1) | 2.0760(11) | Fe(1)-N(1) | 2.1407(11) |
| Zn(1)-N(1)#1 | 2.0760(11) | Fe(1)-N(1)#1 | 2.1408(11) |
| Zn(1)-O(1) | 2.1465(11) | Fe(1)-O(1) | 2.1840(10) |
| Zn(1)-O(1)#1 | 2.1465(11) | Fe(1)-O(1)#1 | 2.1840(10) |
| O(5)-Zn(1)-O(5)#1 | 180 | O(5)-Fe(1)-O(5)#1 | 180 |
| N(1)-Zn(1)-O(5) | 91.61(4) | O(5)-Fe(1)-N(1) | 90.85(4) |
| N(1)-Zn(1)-O(5)#1 | 88.39(4) | O(5)#1-Fe(1)-N(1) | 89.15(4) |
| N(1)#1-Zn(1)-O(5) | 88.39(4) | O(5)-Fe(1)-N(1)#1 | 89.15(4) |
| N(1)#1-Zn(1)-O(5)#1 | 91.61(4) | O(5)#1-Fe(1)-N(1)#1 | 90.85(4) |
| N(1)-Zn(1)-N(1)#1 | 180 | N(1)-Fe(1)-N(1)#1 | 180 |
| O(5)-Zn(1)-O(1)#1 | 88.99(4) | O(5)-Fe(1)-O(1)#1 | 88.44(4) |
| O(5)#1-Zn(1)-O(1)#1 | 91.00(4) | O(5)#1-Fe(1)-O(1)#1 | 91.56(4) |
| N(1)-Zn(1)-O(1)#1 | 100.43(4) | N(1)-Fe(1)-O(1)#1 | 102.61(4) |
| N(1)#1-Zn(1)-O(1)#1 | 79.58(4) | N(1)#1-Fe(1)-O(1)#1 | 77.39(4) |
| O(5)-Zn(1)-O(1) | 91.00(4) | O(5)-Fe(1)-O(1) | 91.56(4) |
| O(5)#1-Zn(1)-O(1) | 89.00(4) | O(5)#1-Fe(1)-O(1) | 88.44(4) |
| N(1)-Zn(1)-O(1) | 79.58(4) | N(1)-Fe(1)-O(1) | 77.39(4) |
| N(1)#1-Zn(1)-O(1) | 100.42(4) | N(1)#1-Fe(1)-O(1) | 102.61(4) |
| O(1)-Zn(1)-O(1)#1 | 180 | O(1)#1-Fe(1)-O(1) | 180 |
Symmetry transformations used to generate equivalent atoms: #1 −x, −y, −z.