Table 4.
Complex | T/K | Ksv (L∙mol−1) | Kq (L∙mol−1∙s−1) | Kb/(L·mol−1) | n | ΔH (kJ·mol−1) | ΔS (J·mol−1·K−1) | ΔG (kJ·mol−1) |
---|---|---|---|---|---|---|---|---|
1 | 298 | 1.06 × 104 | 1.06 × 1012 | 2.20 × 104 | 0.99 | −24.59 | ||
308 | 6.69 × 103 | 6.69 × 1011 | 4.50 × 103 | 0.97 | −98.31 | −247.38 | −22.12 | |
313 | 6.22 × 103 | 6.22 × 1011 | 3.56 × 103 | 0.95 | −20.88 | |||
2 | 298 | 2.22 × 104 | 2.22 × 1012 | 2.62 × 105 | 1.24 | −30.87 | ||
308 | 2.06 × 104 | 2.06 × 1012 | 5.94 × 104 | 1.11 | −108.59 | −260.80 | −28.26 | |
313 | 1.98 × 104 | 1.98 × 1012 | 3.26 × 104 | 1.05 | −26.96 |