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. 2022 Mar 9;122(6):6795–6849. doi: 10.1021/acs.chemrev.1c00493

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© 2022 The Authors. Published by American Chemical Society

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(a) Volumes of H₂ gas generated as functions of reaction time from the dehydrogenation of FA over MMNP (Pd/C, Ag/C, Ni/C), BMNP (Pd_0.55 Ni_0.45/C, Pd_0.52 Ag_0.48/C, Ni_0.58Ag_0.42/C), and TMNP (Pd_0.74Ni_0.12Ag_0.14/C, Pd _0.42Ni_0.36Ag_0.22/C, Pd_0.40Ni_0.16Ag_0.44/C, Pd_0.18Ni_0.38Ag_0.44/C) catalysts. Reaction conditions: [metal] = 2.85 mM and [FA] = [SF] = 0.175 M in 10.0 mL of aqueous solution at 323 K. (b) HRTEM images of PdNiAg/C. (c) Elemental distribution of components in the PdNiAg NPs obtained by line-scan analysis using STEM-EDX along the white arrow in the HAADF-STEM image of PdNiAg/C given in the inset. Adapted with permission from ref (27). Copyright 2014 Elsevier.