Table 1. Summary of a Selection of TMNP Catalysts Applied to CO Hydrogenation to Higher Alcohols.
catalyst | catalyst type | reaction conditions | % CO conversion (selectivity for higher alcohols) | ref |
---|---|---|---|---|
Rh–Mo–K/MWCNT | alkali-promoted BMNP | T = 593 K; p = 8.3 MPa; GHSVa = 3.6 m3 (STP)/(h kg cat) over 24 h; H2/CO molar ratio = 1 | 40.1 (24.6) | (124) |
4.5 wt % Co–Rh–Mo–K/MWCNT | alkali-promoted TMNP | 45.2 (31.4) | ||
6.0 wt % Co–Rh–Mo–K/MWCNT | 48.9 (27.8) | |||
4.5 wt % Co–Rh–Mo–K/AC | 31.2 (18.8) | |||
6.0 wt % Co–Rh–Mo–K/AC | 35.3 (15.9) | |||
4.5 wt % Co–Rh–Mo–K/AC-Darco (microporous) | alkali-promoted TMNP | T = 603 K; p = 8.3 MPa; GHSVa = 3.6 m3 (STP)/(h kg cat) over 48 h; H2/CO molar ratio = 2 | 35.6 (11.7) | (125) |
4.5 wt % Co–Rh–Mo–K/AC-RX3 Extra (microporous) | 39.6 (12.1) | |||
4.5 wt % Co–Rh–Mo–K/AC-Fluid Coke (mesoporous) | 41.8 (12.7) | |||
4.5 wt % Co–Rh–Mo–K/AC-CGP Super (mesoporous) | 44.5 (13.1) | |||
4.5 wt % Co–Rh–Mo–K/MWCNTs | 52.4 (16.8) |
Gas hourly space velocity.