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. 2022 Mar 9;122(6):6795–6849. doi: 10.1021/acs.chemrev.1c00493

Table 1. Summary of a Selection of TMNP Catalysts Applied to CO Hydrogenation to Higher Alcohols.

catalyst catalyst type reaction conditions % CO conversion (selectivity for higher alcohols) ref
Rh–Mo–K/MWCNT alkali-promoted BMNP T = 593 K; p = 8.3 MPa; GHSVa = 3.6 m3 (STP)/(h kg cat) over 24 h; H2/CO molar ratio = 1 40.1 (24.6) (124)
4.5 wt % Co–Rh–Mo–K/MWCNT alkali-promoted TMNP 45.2 (31.4)
6.0 wt % Co–Rh–Mo–K/MWCNT 48.9 (27.8)
4.5 wt % Co–Rh–Mo–K/AC 31.2 (18.8)
6.0 wt % Co–Rh–Mo–K/AC 35.3 (15.9)
4.5 wt % Co–Rh–Mo–K/AC-Darco (microporous) alkali-promoted TMNP T = 603 K; p = 8.3 MPa; GHSVa = 3.6 m3 (STP)/(h kg cat) over 48 h; H2/CO molar ratio = 2 35.6 (11.7) (125)
4.5 wt % Co–Rh–Mo–K/AC-RX3 Extra (microporous) 39.6 (12.1)
4.5 wt % Co–Rh–Mo–K/AC-Fluid Coke (mesoporous) 41.8 (12.7)
4.5 wt % Co–Rh–Mo–K/AC-CGP Super (mesoporous) 44.5 (13.1)
4.5 wt % Co–Rh–Mo–K/MWCNTs 52.4 (16.8)
a

Gas hourly space velocity.