Table 4. Summary of Catalysts for Dehydrogenation of Formic Acid.

catalyst	catalyst type	reaction conditions	performance	ref
AgPd/C	supported BMNP	323 K	TOF = 382 h–1	(242)
Pd/C	spported MMNP		TOF = 75 h–1; volume of H2 generated after 140 min = 63 mL	(27)
Ni/C	supported MMNP		TOF = 4 h–1; volume of H2 generated after 140 min = 4 mL
Ag/C	supported MMNP		TOF = 2 h–1; volume of H2 generated after 140 min = 2 mL
Pd0.58Ni0.18Ag0.24/C	supported TMNP		TOF = 85 molH2 molcat–1 h–1; volume of H2 generated after 140 min = 76 mL
Pd/C	supported MMNP	T = 298 K; p = 0.1 MPa	TOF = 8.3 h–1; formic acid conversion after 600 min = 39%	(77)
Ni/C	supported MMNP		formic acid conversion after 600 min = 2%
Au/C	supported MMNP		formic acid conversion after 600 min = 0%
Ni0.4Pd0.6/C	supported BMNP		TOF = 8.4 h–1; formic acid conversion after 600 min = 52%
Au0.25Pd0.75/C	supported BMNP		TOF = 10.1 h–1; formic acid conversion after 600 min = 42%
Ni0.4Au0.6/C	supported BMNP		formic acid conversion after 600 min = 1%
Ni0.4Au0.15Pd0.45/C	supported TMNP		TOF = 12.4 h–1; formic acid conversion after 600 min = 73%
physical mixture of Ni/C, Au/C, and Pd/C (Ni:Au:Pd = 0.4:0.15:0.45)	mixture of MMNPs		TOF = 3.7 h–1; formic acid conversion after 600 min = 22%
PdAg@Fe	core@shell TMNP	303 K	kobs = 0.328 h–1 (TOF = 30 molH2 molcat–1 h–1)	(252)
FePd@Ag	core@shell TMNP		kobs = 0.540 h–1 (TOF = 49 molH2 molcat–1 h–1)
FeAg@Pd	core@shell TMNP		kobs = 0.828 h–1; CO2 + H2 generated after 120 min = 88 mL; TOF = 75 molH2 molcat–1 h–1
PdCuCr	TMNP constructed in situ	348 K; HCOOH/HCOONa = 9:1 aqueous solution	H2 production rate = 174 000 mL h–1 gPd–1; TOF = 830 h–1	(251)