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. 2022 Mar 9;122(6):6795–6849. doi: 10.1021/acs.chemrev.1c00493

Table 7. Catalytic Performance of a Variety of Supported and Unsupported TMNP, BMNP, and MMNP Formulations for the Ammonia Borane Dehydrogenation Reaction.

catalyst catalyst type reaction temperature (K) TOF (h–1) ref
Pt76Au12Co12 TMNP alloy 298 27000 (78)
Pt76Au11Co13 23460
Pt74Au21Co5 15900
Pt80Au16Co4 15540
Pt78Au6Co16 6000
Pt56Au4Co40 5640
Pt85Au15 BMNP alloy 8220
Pt86Co14 3960
Au@Co BMNP core@shell 840
Pt MMNP 240
Au 180
Co 120
Pt (black) MMNP 298 840 (258)
Ru@Co BMNP core@shell 298 20640 (259)
AuCo/CN supported BMNP 303 2880 (260)
PtCo BMNP 293 18180 (261)
PtCu BMNP 298 6480 (262)
Cu40Co60/BN supported BMNP 298 480 (263)
PtCoCu@SiO2 protected TMNP 303 16380 (264)
Cu72Co18Mo10 TMNP 298 7140 (265)
CuNiCo/MOF supported TMNP 298 4200 (266)
RuCuNi/CNTs supported TMNP 298 18669 (28)