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. 2022 Mar 9;10:845452. doi: 10.3389/fchem.2022.845452

TABLE 2.

The concentration (mg/l) of the content in heavy metal in the samples.

ppm Fe V Cr Mn Zn Ba
MK 15–64 0.1–0.2 <0.1 0.1–2 0.1–0.2 0.1–0.7
FA 14–87 0.1–0.3 0.1–0.2 0.0–2 0.0–0.4 0.0–0.8
FA33K S.T. 29–35 0.1–0.2 <0.1 0.6–0.7 0.1–0.2 0.1–0.2
FA36Na S.T. 37–41 0.1–0.2 <0.1 0.8–0.9 0.1 0.3
FA67K S.T. 41–49 0.1–0.2 <0.1 1.3–1.4 0.2–0.3 0.3–0.4
FA67K 1,000 46–52 0.1–0.2 <0.1 1.4–1.7 0.2–0.3 0.3

The following elements were found in amounts lower than 0.1 ppm: Co, Ni, Cu, As, Se, Ag, Cd, Sb, Tl, Pb, and Be.

The lower limit of detection is 2 μg/l, while the upper limit of detection is 500 μg/l. When solutions were too concentrated, dilutions to 1:100 or 1: 1,000 were operated. Due to sample homogeneity and preparation procedure, the error affecting these results is around 30%.