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. Author manuscript; available in PMC: 2022 Dec 22.
Published in final edited form as: Chem Rev. 2021 Oct 29;121(24):14957–15074. doi: 10.1021/acs.chemrev.1c00519

Scheme 121.

Scheme 121

a) Palladium-Catalyzed Alkoxycarbonylation of Unactivated β-Methylene C(sp3)–H Bonds with Alkyl Chloroformates (Shi et al., 2016).333 b) Synthesis of Stable CO-Coordinated Palladacycles and Mechanistic Studies (Wang et al., 2019)334