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. 2021 Jul 20;23(30):16390–16400. doi: 10.1039/d1cp02162a

HCl photodissociation cross sections and rates for the A1Π ← X1Σ+ electronic transition, using different smoothing methods. λmax is in nm, σmax in cm2 molecule−1 and k in s−1.

Model λ max σ max k
Experimental41 153.00 ± 0.05 3.82 ± 0.38 × 10−18
Experimental42 153.90 ± 0.05 3.28 ± 0.49 × 10−18
Experimental43 153.90 ± 0.02 3.53 ± 0.18 × 10−18
van Dishoeck et al.44 154.4 3.5 × 10−18 2.1 × 10−10
PHOTO 153.63 3.644 × 10−18 2.188 × 10−10
Raw data 155.21 1.472 × 10−16 2.289 × 10−10
Gaussian smooth 156.76 3.553 × 10−18 2.290 × 10−10
Interpolation 156.88 4.135 × 10−18 2.290 × 10−10