Screening the reaction parameters for the synthesis of 6d.
| |||
|---|---|---|---|
| Entry | Fe3−xBixO4/SiO2@l-ArgEt3+I−/Zn(ii) (g)/solvent (3 mL)/temperature (°C) | Time (h) | Yield (%) |
| 1 | 0.032/—/rt | 24 | 32 |
| 2 | 0.032/—/60 | 12 | 20 |
| 3 | 0.032/H2O/rt | 16 | 10 |
| 4 | 0.032/EtOH/rt | 16 | 62 |
| 5 | 0.04/EtOH/rt | 12 | 51 |
| 6 | 0.02/EtOH/rt | 16 | 67 |
| 7 | 0.024/EtOH/rt | 20 | 67 |
| 8 | 0.012/EtOH/rt | 9 | 83 |
| 9 | 0.012/EtOH–H2O (1 : 1)/rt | 12 | 10 |
| 10 | 0.012/EtOH–H2O (1 : 1)/50 | 10 | 40 |
| 11 | 0.012/PEG (2000)/rt | 10 | 5 |
| 12 | 0.012/EtOH/0 | 20 | — |