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. 2022 Mar 18;7(12):9984–9994. doi: 10.1021/acsomega.1c07123

Table 1. Advantages and Disadvantages of Various Approaches to Injecting CO2 into Subsurface Reservoirs7,9,10.

approach definition advantages disadvantages limitations
carbonated water injection carbonated water injection is the simplest way of supplying CO2 to reservoirs and involves the injection of water saturated with CO2 to the maximum of (3–5 wt %) displacement of oil by carbonated water is accompanied by a significant lag of the front of the concentration of CO2 in water from the front of oil displacement, which depends on the distribution coefficient of CO2 between oil and water, its concentration in water, as well as the pressures and temperatures of the reservoir conditions; this leads to a significant increase in the time taken to obtain beneficial effects from the use of technology relatively low consumption of CO2 (6–7 times less) during injection into the reservoir compared to other techniques low permeability or moderately homogeneous reservoirs are the only suitable candidates for this process
continuous CO2 injection in the gaseous phase this method is widely used to displace residual oil in a flooded reservoir by continuous injection of carbon dioxide it achieves a higher oil displacement ratio than other CO2 technologies; this is due to the fact that in front of the advancing front of CO2 an oil swell is formed, which is characteristic of processes with miscible displacement rapid breakthroughs of CO2 to production wells through highly permeable formations, gravity separation, and significant reduction in sweep efficiency are possible after primary recovery, this technique is suitable for reservoirs with light to medium gravity oil and those that are highly flooded or strongly water-wet
displacement of oil by CO2 alone requires large expenditures
cyclic injection of CO2 into injection wells this method makes it possible to develop low-permeability, heterogeneous reservoirs by cyclic injection of CO2; this improves upon continuous CO2 injection which tends to be less effective, more costly, and impractical it is possible to increase both the coefficient of oil displacement by CO2 and the coefficient of reservoir sweep, as well as to minimize the risk of gas breakthrough into the producing wells displacement of oil by CO2 alone requires large expenditures suitable for reservoirs exhibiting different zones of permeability.
injection of mixtures of captured flue gases compositions of flue gases vary but typically include air-polluting components, some of which including CO2 could be captured flue gases are low cost to obtain, and their sequestration would serve to reduce air pollution of the environment gases other than CO2 mix well only with lighter crude oils strong dependence of the displacement of oil by gaseous CO2 slugs on the conditions of gravity separation limits the use of this technology in reservoirs with high vertical permeability.
alternating injection of CO2 and water by injecting the required volume of CO2 in small portions, alternately or simultaneously with water, a higher efficiency of CO2 EOR can be achieved; in this case, the duration between cycles depends on the density of the well spacings and patterns of injectors and producers; that duration can vary from several hours to a month or more effective way of enhancing oil recovery for low-permeability oil reservoirs low permeability and poor pore space connectivity in some reservoirs limit injection rates technology can be applied as part of an existing reservoir pressure maintenance system and used both at individual wells and/or across an entire reservoir involving multiple wells
in heterogeneous formations with high crude oil viscosity, the quantities of water and gas injected should be lower
surface equipment toggling between CO2 and water injection is required
CO2-foam injection technology these methods are based on the use of foams, a process that controls the movement of CO2 by generating foam (dispersing CO2 in a liquid phase) use of foam helps to achieve better oil displacement compared to waterflooding or the above CO2 injection technologies CO2-foam injection technology is a lengthy process this technology is suitable for highly heterogeneous reservoirs with some highly permeable/porous layers and some oil-depleted zones with high water saturations
the method reduces the gravitational separation of fluids and stabilizes the displacement front composition of the surfactant is likely to be unstable under harsh reservoir conditions
foaming surfactant solutions more strongly reduce the relative permeability of the pore space for gas than water; foam surfactant properties can be improved with NP additives possibility exists for superficial absorption of the foams by the reservoir rocks; moreover, in some reservoirs, the surfactant around CO2 bubbles might not be effective as foam flows through constricted pore throats
gas-cyclic injection and production through the same wellbores (“huff-n-puff” process) this involves the injection of CO2 directly into a production well with its subsequent shutdown for soaking the bottom hole formation zone and subsequent oil production this technology can significantly reduce capital costs for the implementation of the technology since it does not require the construction of special injection wells asphaltene dropout injection of CO2 under supercritical conditions is suitable for deep low-permeability reservoirs and those associated with water drives
this method makes it possible to implement the delivery of liquefied CO2 by road, which can be a more profitable option in some cases possible equipment corrosion
need to separate and capture recycled CO2 from oil and associated gas ultimately produced
stability of equipment seals