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. 2021 Dec 22;12(1):602–610. doi: 10.1039/d1ra05804e

Hydrogenation of LA to GVL in various solvents over Cu–Re(1 : 1)/TiO2 catalysta.

Solvent Conversion (%) Selectivity (%)
GVL HVAb
1,4-Dioxane 98.9 98.6 1.1
H2O >99.9 >99.9 0
Methanol 100 88.1 11.9
No solvent 97.3 97.6 2.4
a

Reaction conditions: 0.5 g LA, 50 mg catalyst, 10 mL solvent, 4.0 MPa H2, 180 °C, 3 h, and 1000 rpm.

b

HVA: 4-hydroxyvaleric acid.