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. 2022 Feb 7;12(8):4656–4671. doi: 10.1039/d1ra04762k

Shifting of Raman peaks (Δω) with grain size, (XA), Poisson's ratio (σ), anisotropy factor (A), Debye temperature (θD), Curie temperature (TC) and exchange interaction (J) obtained for Ni0.7Zn0.2Co0.1Fe2−xGdxO4 (0 ≤ x ≤ 0.12).

Gd content (x) Δω X A (nm) σ A (GPa) T C (K) J (J) × 10−14 θ D (K)
0.00 0.00 81.7 ± 1 0.30 0.53 731 2.52 685.67
0.02 27.12 56.1 ± 3.8 0.30 0.54 718 2.48 680.85
0.05 92.99 55.3 ± 1.9 0.29 0.55 715 2.47 680.85
0.07 93 50.9 ± 2.8 0.31 0.53 713 2.46 680.45
0.10 97.99 42.9 ± 0.9 0.30 0.53 712 2.45 678.01
0.12 96.86 45.0 ± 0.03 0.30 0.53 711 2.45 675.97