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. 2022 Mar 8;78(Pt 4):359–364. doi: 10.1107/S2056989022002420
C11—N12 1.362 (4) C21—H21 0.9500
C11—N17A 1.363 (4) N22—C23 1.338 (4)
C11—C17A 1.363 (4) N22—C22 1.470 (4)
C11—H11 0.9500 C22—H22A 0.9800
N12—C13 1.338 (4) C22—H22B 0.9800
N12—C12 1.462 (4) C22—H22C 0.9800
C12—H12A 0.9800 C23—C23A 1.346 (4)
C12—H12B 0.9800 C23—N23A 1.346 (4)
C12—H12C 0.9800 C23—H23 0.9500
C13—C13A 1.347 (4) N23A—C24 1.398 (4)
C13—N13A 1.347 (4) N23A—C27A 1.399 (4)
C13—H13 0.9500 C23A—C24 1.398 (4)
N13A—C17A 1.402 (4) C23A—N27A 1.399 (4)
N13A—C14 1.402 (4) C24—C25 1.355 (5)
C13A—N17A 1.402 (4) C24—H24 0.9500
C13A—C14 1.402 (4) C25—C26 1.416 (5)
C14—C15 1.350 (5) C25—H25 0.9500
C14—H14 0.9500 C26—C27 1.347 (5)
C15—C16 1.425 (5) C26—H26 0.9500
C15—H15 0.9500 C27—N27A 1.420 (4)
C16—C17 1.348 (5) C27—C27A 1.420 (4)
C16—H16 0.9500 C27—H27 0.9500
C17—N17A 1.413 (4) Cd1—Cl3 2.4481 (8)
C17—C17A 1.413 (4) Cd1—Cl2 2.4654 (16)
C17—H17 0.9500 Cd1—Cl4 2.4655 (7)
C21—N27A 1.360 (4) Cd1—Cl1 2.4710 (7)
C21—C27A 1.360 (4) Cd1—I2 2.747 (4)
C21—N22 1.364 (4)
N12—C11—N17A 107.1 (3) C23—N22—C22 124.4 (3)
N12—C11—C17A 107.1 (3) C21—N22—C22 125.1 (3)
N12—C11—H11 126.4 N22—C22—H22A 109.5
C17A—C11—H11 126.4 N22—C22—H22B 109.5
C13—N12—C11 110.5 (2) H22A—C22—H22B 109.5
C13—N12—C12 125.3 (3) N22—C22—H22C 109.5
C11—N12—C12 124.2 (2) H22A—C22—H22C 109.5
N12—C12—H12A 109.5 H22B—C22—H22C 109.5
N12—C12—H12B 109.5 N22—C23—C23A 107.4 (3)
H12A—C12—H12B 109.5 N22—C23—N23A 107.4 (3)
N12—C12—H12C 109.5 N22—C23—H23 126.3
H12A—C12—H12C 109.5 N23A—C23—H23 126.3
H12B—C12—H12C 109.5 C23—N23A—C24 130.1 (3)
N12—C13—C13A 107.3 (3) C23—N23A—C27A 108.4 (3)
N12—C13—N13A 107.3 (3) C24—N23A—C27A 121.5 (3)
N12—C13—H13 126.3 C23—C23A—C24 130.1 (3)
N13A—C13—H13 126.3 C23—C23A—N27A 108.4 (3)
C13—N13A—C17A 108.5 (2) C24—C23A—N27A 121.5 (3)
C13—N13A—C14 131.1 (3) C25—C24—N23A 118.1 (3)
C17A—N13A—C14 120.4 (3) C25—C24—C23A 118.1 (3)
C13—C13A—N17A 108.5 (2) C25—C24—H24 120.9
C13—C13A—C14 131.1 (3) N23A—C24—H24 120.9
N17A—C13A—C14 120.4 (3) C24—C25—C26 121.3 (3)
C15—C14—N13A 118.6 (3) C24—C25—H25 119.3
C15—C14—C13A 118.6 (3) C26—C25—H25 119.3
C15—C14—H14 120.7 C27—C26—C25 121.2 (3)
N13A—C14—H14 120.7 C27—C26—H26 119.4
C14—C15—C16 121.1 (3) C25—C26—H26 119.4
C14—C15—H15 119.5 C26—C27—N27A 118.9 (3)
C16—C15—H15 119.5 C26—C27—C27A 118.9 (3)
C17—C16—C15 121.4 (3) C26—C27—H27 120.5
C17—C16—H16 119.3 C27A—C27—H27 120.5
C15—C16—H16 119.3 C21—C27A—N23A 106.9 (3)
C16—C17—N17A 118.2 (3) C21—C27A—C27 134.1 (3)
C16—C17—C17A 118.2 (3) N23A—C27A—C27 119.0 (3)
C16—C17—H17 120.9 C21—N27A—C23A 106.9 (3)
C17A—C17—H17 120.9 C21—N27A—C27 134.1 (3)
C11—C17A—N13A 106.5 (2) C23A—N27A—C27 119.0 (3)
C11—C17A—C17 133.2 (3) Cl3—Cd1—Cl2 109.94 (9)
N13A—C17A—C17 120.3 (3) Cl3—Cd1—Cl4 116.91 (3)
C11—N17A—C13A 106.5 (2) Cl2—Cd1—Cl4 106.67 (9)
C11—N17A—C17 133.2 (3) Cl3—Cd1—Cl1 105.93 (3)
C13A—N17A—C17 120.3 (3) Cl2—Cd1—Cl1 112.21 (9)
N27A—C21—N22 106.9 (3) Cl4—Cd1—Cl1 105.20 (3)
C27A—C21—N22 106.9 (3) Cl3—Cd1—I2 109.2 (2)
C27A—C21—H21 126.6 Cl2—Cd1—I2 0.9 (3)
N22—C21—H21 126.6 Cl4—Cd1—I2 106.7 (2)
C23—N22—C21 110.5 (3) Cl1—Cd1—I2 113.0 (2)
N17A—C11—N12—C13 −0.2 (3) N27A—C21—N22—C23 0.5 (3)
C17A—C11—N12—C13 −0.2 (3) C27A—C21—N22—C23 0.5 (3)
N17A—C11—N12—C12 178.3 (3) N27A—C21—N22—C22 −178.3 (3)
C17A—C11—N12—C12 178.3 (3) C27A—C21—N22—C22 −178.3 (3)
C11—N12—C13—C13A −0.3 (3) C21—N22—C23—C23A −0.7 (3)
C12—N12—C13—C13A −178.7 (2) C22—N22—C23—C23A 178.1 (3)
C11—N12—C13—N13A −0.3 (3) C21—N22—C23—N23A −0.7 (3)
C12—N12—C13—N13A −178.7 (2) C22—N22—C23—N23A 178.1 (3)
N12—C13—N13A—C17A 0.6 (3) N22—C23—N23A—C24 179.8 (3)
N12—C13—N13A—C14 −177.6 (3) N22—C23—N23A—C27A 0.5 (3)
N12—C13—C13A—N17A 0.6 (3) N22—C23—C23A—C24 179.8 (3)
N12—C13—C13A—C14 −177.6 (3) N22—C23—C23A—N27A 0.5 (3)
C13—N13A—C14—C15 178.5 (3) C23—N23A—C24—C25 −179.5 (3)
C17A—N13A—C14—C15 0.4 (4) C27A—N23A—C24—C25 −0.4 (4)
C13—C13A—C14—C15 178.5 (3) C23—C23A—C24—C25 −179.5 (3)
N17A—C13A—C14—C15 0.4 (4) N27A—C23A—C24—C25 −0.4 (4)
N13A—C14—C15—C16 0.7 (5) N23A—C24—C25—C26 −1.0 (4)
C13A—C14—C15—C16 0.7 (5) C23A—C24—C25—C26 −1.0 (4)
C14—C15—C16—C17 −0.9 (5) C24—C25—C26—C27 1.4 (5)
C15—C16—C17—N17A −0.2 (5) C25—C26—C27—N27A −0.4 (4)
C15—C16—C17—C17A −0.2 (5) C25—C26—C27—C27A −0.4 (4)
N12—C11—C17A—N13A 0.5 (3) N22—C21—C27A—N23A −0.2 (3)
N12—C11—C17A—C17 179.7 (3) N22—C21—C27A—C27 178.7 (3)
C13—N13A—C17A—C11 −0.7 (3) C23—N23A—C27A—C21 −0.2 (3)
C14—N13A—C17A—C11 177.8 (3) C24—N23A—C27A—C21 −179.6 (2)
C13—N13A—C17A—C17 −180.0 (2) C23—N23A—C27A—C27 −179.3 (3)
C14—N13A—C17A—C17 −1.5 (4) C24—N23A—C27A—C27 1.4 (4)
C16—C17—C17A—C11 −177.7 (3) C26—C27—C27A—C21 −179.7 (3)
C16—C17—C17A—N13A 1.4 (4) C26—C27—C27A—N23A −1.0 (4)
N12—C11—N17A—C13A 0.5 (3) N22—C21—N27A—C23A −0.2 (3)
N12—C11—N17A—C17 179.7 (3) N22—C21—N27A—C27 178.7 (3)
C13—C13A—N17A—C11 −0.7 (3) C23—C23A—N27A—C21 −0.2 (3)
C14—C13A—N17A—C11 177.8 (3) C24—C23A—N27A—C21 −179.6 (2)
C13—C13A—N17A—C17 −180.0 (2) C23—C23A—N27A—C27 −179.3 (3)
C14—C13A—N17A—C17 −1.5 (4) C24—C23A—N27A—C27 1.4 (4)
C16—C17—N17A—C11 −177.7 (3) C26—C27—N27A—C21 −179.7 (3)
C16—C17—N17A—C13A 1.4 (4) C26—C27—N27A—C23A −1.0 (4)