Table 3. Experimental details.

Crystal data
Chemical formula	[Ti(C6H4O2)2(C2H6OS)2]
M r	420.34
Crystal system, space group	Monoclinic, P21/c
Temperature (K)	100
a, b, c (Å)	12.4531 (3), 14.7287 (3), 20.3676 (5)
β (°)	90.0445 (9)
V (Å3)	3735.78 (15)
Z	8
Radiation type	Mo Kα
μ (mm−1)	0.71
Crystal size (mm)	0.35 × 0.23 × 0.09
Data collection
Diffractometer	Nonius Kappa CCD
Absorption correction	Multi-scan (SCALEPACK; Otwinowski & Minor, 1997 ▸)
T min, T max	0.668, 0.939
No. of measured, independent and observed [I > 2σ(I)] reflections	39962, 8552, 7393
R int	0.047
(sin θ/λ)max (Å−1)	0.666
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.036, 0.073, 1.04
No. of reflections	8552
No. of parameters	461
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	0.41, −0.45

Computer programs: COLLECT (Nonius, 1998 ▸), HKL-3000 (Otwinowski & Minor, 1997 ▸), SHELXS97 (Sheldrick, 2008 ▸), SHELXL2018/3 (Sheldrick, 2015 ▸), ShelXle (Hübschle et al., 2011 ▸), Mercury (Macrae et al., 2020 ▸), and publCIF (Westrip, 2010 ▸).