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(shNC group, shATP7B + Cu group, and GDD group) OPLS-DA score and its corresponding S-plot for differential analysis between different groups of cell samples in RPLC-Q-TOF/MS negative and positive ESI mode. [(A). NEG-R2Y = 99%, Q2 = 97%; (B). NEG-R2Y = 99%, Q2 = 99%; (C). POS- R2Y = 1, Q2 = 99%; (D). POS- R2Y = 1, Q2 = 99%].
