The X-ray Ag–N and Ag⋯X (X = F, O) distances, density (ρ, a.u.) at the bond CPs represented in Fig. 8 and Wiberg bond indexes (WBI) for all the silver(i) complexes synthesised in this work.

Complex	Ag–N	Ag–X	ρ × 102	WBI (Ag–N)
1a	2.151	2.990	0.97	0.164 & 0.159
1e	2.150 & 2.155	2.828	1.46	0.144 & 0.150
1f	2.170 & 2.175	2.685	2.23	0.138 & 0.133
2a	2.210	2.818	1.45	0.092 & 0.095
2e	2.215 & 2.219	2.743	1.75	0.081 & 0.091
2f	2.224 & 2.223	2.578	2.67	0.080 & 0.082