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. 2022 Mar 17;12(14):8414–8422. doi: 10.1039/d1ra09455f

Selected bond distances (Å) in 1 and in [RuCl(trpy)(bpy)](PF6), and their differences Δr (Å).

Bonda 1 [RuCl(trpy)(bpy)](PF6)b Δr
Ru1–N10 1.977 1.951 0.026
Ru1–N3 2.073 2.059 0.014
Ru1–N20 2.084 2.070 0.014
Ru1–N24 2.050 2.031 0.019
Ru1–N35 2.093 2.069 0.024
Ru1–Cl 2.431 2.397 0.034
a

Numbering of N atoms are shown in Fig. 1.

b

Crystallographic data obtained from the Cambridge Crystallographic Data Centre (CCDC, 789502).