Parameters of thermodynamic activation of corrosion of carbon steel in 1 M hydrochloric acid in the presence and absence of Eruca sativa seeds extract at different concentrations.
| Inhibitor conc. (g L−1) |
|
ΔH*, kJ mol−1 | −ΔS*, J mol−1 K−1 | log A |
|---|---|---|---|---|
| Blank | 5.12 | 18.60 | 194.74 | 0.483 |
| 0.05 | 42.89 | 40.40 | 131.73 | 6.35 |
| 0.10 | 45.88 | 43.85 | 121.78 | 6.77 |
| 0.15 | 52.46 | 48.54 | 107.66 | 7.78 |
| 0.20 | 54.15 | 53.61 | 93.82 | 8.11 |
| 0.25 | 59.16 | 54.50 | 90.43 | 8.8 |
| 0.30 | 63.18 | 58.59 | 79.65 | 9.4 |