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. 2022 Mar 22;12(15):8852–8861. doi: 10.1039/d2ra00795a

General properties of Co-TLCP hybrids containing various HQ mole ratios.

HQ in TLCP (mole ratio) IVa T g (°C) T m (°C) ΔHm (J g−1) T i (°C) ΔHi (J g−1) T i b (°C) wtR600c (%) LC phase DCd (%)
1 1.50 94 148 3.43 217 1.91 300 31 Nem.e 29
2 1.94 95 147 3.15 219 1.59 310 29 Nem. 30
3 1.89 100 208 1.19 258 1.06 329 27 Nem. 35
4 1.67 103 210 0.31 259 7.35 340 29 Nem. 40
5 1.84 108 269 2.52 352 30 Nem. 36
a

Inherent viscosity was measured at a concentration of 0.1 g dL−1 solution in phenol/p-chlorophenol/tetrachloroethane = 25/40/35 (w/w/w) at 25 °C.

b

At a 2% initial weight-loss temperature.

c

Weight % of residue at 600 °C.

d

Degree of crystallinity.

e

Nematic schlieren texture.