Prod.	X	R1	Yield	t (min)	TON	TOF
9a	I	NH2	85	120	180	90
9a	Cl	NH2	65	150	138	39
9b	I	OMe	92	70	195	168
9b	Br	OMe	90	110	191	104
9c	I	Me	85	90	180	120
9c	Br	Me	75	120	159	79
9c	Cl	Me	65	150	138	55
9d	I	H	95	15	202	808
9d	Br	H	95	20	202	612
9d	Cl	H	92	100	195	117
9e	I	CHO	93	60	197	197
9e	Br	CHO	85	85	180	128
9e	Cl	CHO	75	100	195	96
9f	Br	COMe	95	90	202	134
9g	I	NO2	94	25	200	487
9g	Br	NO2	90	35	191	330
9g	Cl	NO2	87	55	155	155
9h	Br	CN	80	90	170	113
9h	Cl	CN	60	180	148	49

^aReaction conditions: phenylboronic acid (1.2 mmol), aryl halide (1.00 mmol), K₂CO₃ (Et₃N when we used the aryl chlorides) (2.00 mmol), catalyst (0.007 g, 0.47 mol% of Pd), H₂O (2.0 mL), 60 °C (90 °C when we used the aryl chlorides); all yields are isolated.