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. 2022 Mar 22;7(13):11114–11125. doi: 10.1021/acsomega.1c07193

Table 6. Comparison of Our Sensor to Some of Imidazole-Based Chemosensors Reported in the Literature for Sensing Cu2+, Fe2+, and Fe3+.

sensor method ions media used binding constant LOD binding ratio mechanism involved ref.
(E)7(diethylamino)3((2phenylimidazo[1,2-a]pyridinylimino)methyl)-2H-chromen-2-one colorimetric and fluorometric Cu2+ DMSO, water 4.859 × 103 M–1 4.6 × 10–8 M 1:1 ICT and CHEF (56)
triazole-appended imidazopyridine sensor fluorometric Cu2+, CN CH3CN, water 3.12 × 10–8 M–1 18.17× 10–6 M 1:1 MLCT (57)
furan-2-yl substituted imidazoazine-based sensor colorimetric and fluorometric Cu2+ CH3OH, water ∼104 M–1 ∼10–7 M 1:1 paramagnetic quenching (58)
2-(3-(tert-butylamino)imidazo[1,2-a]pyridin-2yl) phenol colorimetric and fluorometric Al3+, Fe3+,Cr3+ CH3CN 2.77 × 106 M–1 1.9 × 10–9 M 1:1 attainment of coplanarity and CHEF (59)
3-(4-methoxyphenyl)- 1-phenylbenzo[4,5]imidazo[1,2-a]-pyridine fluorometric Fe3+, Hg2+ EtOH, water 1.09 × 105 M1 4.0 ppb 1:1 LMCT and CHEF (60)
(E)-5-((4-(diethylamino)-2-hydroxybenzyldene)amino)-1H-imidazole-4-carboxamide colorimetric Fe3+, Fe2+ bis–tris buffer 5.0 × 1010 M–1 (Fe3+) and 1.0 × 1010 M–1 (Fe2+ ) 0.73 μM (Fe3+) 1.11 μM (Fe2+) 2:1   (61)
3,4-dimethoxyphenyl)(4-(3,4-dimethoxyphenyl)-1H-imidazol-2-yl) methanone oxime fluorometric Fe3+ DMSO     1:1 ESIPT and LMCT (62)
present sensors (SS1 and SS2) colorimetric and fluorometric Cu 2+, Fe2+, Fe3+ THF, water ∼104 ∼10–6 1:1 (Cu2+), 2:1 (Fe2+, Fe3+) ICT