Skip to main content
. 2022 Mar 29;27(7):2226. doi: 10.3390/molecules27072226

Table 2.

The hazardous metal ion detection ability and detection mechanisms of various LMOF-based sensors.

Entries Analyte MOF Detection
Limit
Detection Mechanism Refs
Entry 1 Pb2+ [Tb(L)(H2O)5]n 107 M QD [70]
{[Cd(BIPA)(IPA)]·DMF}n 7.5 × 107 M QD [71]
{[Cd(BIPA)(HIPA)]·DMF}n 5.0 × 107 M
Zn-TCPP-MOF 4.99 × 108 M - [73]
SO3H-UiO-66(Zr) 25.2 ppm QD [74]
Hg2+ UiO-66@butyne 10.9 nmol/L QD [79]
NH2-MIL-53(Al) 0.15 μM QD [80]
Zn2(NDC)2(DPTTZ) - FRET [81]
[Ni3(BTC)2(H2O)3]·(DMF)3(H2O)3 0.02 μM QD [83]
Cd2+ Zr-based LMOF 0.002 μM PET [85]
[Zn2(tdca)2(bppd)2]·2DMF 0.132 μM PET [86]
Entry 2 UO22+ Tb-MOF 0.9 μg/L PET [89]
[Eu2(MTBC)(OH)2(DMF)3(H2O)4]·2DMF·
7H2O
309.2 μg/L PET [90]
(CH3)2NH2[Ln2(BTC)(AC)3(FM)] 4.12 μM QD [91]
[M(HBTC)(BMIOPE)·DMF·H2O]n 2.47 × 105 M FRET [93]
Cd-MOF 8.5 μg/L PET [94]
Th4+ [Eu2(FDC)3(DMA)2]·4H2O 3.49 × 105 mol/L PET
FRET
[95]
[Ln2(NH2-BDC)2.5(CH3COO)(DMA)(H2O)]·DMA 3.40 μM QD [96]
99TcO4− [1H6(ReO4)](CF3-SO3)5·7H2O - PET [97]
Cd(II)-MOFs 0.68 × 104 M−1 - [98]
ReO4 [Zr6O4(OH)4(NH3+-BDC)6]Cl6·xH2O (MOR-1) 0.36 ppm PET [99]
H16[Zr6O16(H2PATP)4]Cl8·xH2O (MOR-2) 0.20 ppm
[Ag(1,2,4,5-p4b)](SbF6) (TJNU-302) - FRET
ESIPT
[100]