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. 2022 Mar 31;15(7):2565. doi: 10.3390/ma15072565

Table 1.

Absorption signals of Fourier transform infrared spectroscopy for the spectrum of hemp fibers.

Name of the Function Group Wavenumber
[cm−1]
Bibliographic
C-OH out-of-plane bending vibrations; C-C 557 [46]
Stretch vibrations of the glucose ring;
C–H stretching vibrations outside the plane of the aromatic ring
895 [22,23]
-OH; -COO 900–1200 [47]
CO-O-CO 1000–1100 [48]
C-O stretching vibrations; deformation of the C-H aromatic plane 1030–1058 [49,50]
The absorption band of hydroxyl compounds -OH 1100 [51,52]
C-O stretching vibrations; asymmetric bridge C-O-C stretching vibrations 1158 [52,53]
C-O; C=O; C-C-; COOH 1100–1300 [54]
Acyl-oxygen CO-OR stretching vibrations in hemicelluloses; -CH3 1245 [50]
C-H deformation vibrations; -OH bending vibrations 1325 [51]
C-H bending vibrations related to the structure of cellulose and hemicellulose 1369 [53,55]
CH2 stretching vibrations related to the cellulose structure, vibrations of the bonds of the aromatic backbone 1425–1426 [52,53,56,57]
CH deformation vibrations; asymmetric bending vibrations from -CH2 and -CH3 groups 1426–1463 [46]
C=C stretching vibrations in aromatic structures 1508 [51]
C=C stretching of the aromatic ring 1550 [45]
C=C unsaturated bonds; 1592 [51]
COO (pectin) 1650 [45]
-OH from absorbed water; C=C 1653 [50,51,56,58]
C=O stretching vibrations in uncoupled ketones and free aldehydes 1736; 1718 [55,56,57,59,60]
CH stretching vibrations in methyl and methylene groups 2896 [53,55,61]
-OH stretching vibrations (hydrogen bonds) 3331 [53,62]