Table 1.
Type | Fabrication [26,28,39,44] |
Structure [26,27,39,46] |
Size [26,27,28,46,69,70] |
---|---|---|---|
CMF | Mechanical treatment | Long thin flexible aggregates of elementary fibrils/microfibrils with amorphous and crystalline domains | Width 20–100 nm Length 0.5—several μm |
CNF | Mechanical with/without chemical and/or enzymatic treatment | Long thin flexible structures with amorphous and crystalline domains | Width 2–100 nm Length 0.5—several μm |
CMC | Hydrolysis with diluted inorganic acids with/without mechanical treatment | Rigid crystalline spherical or rod-shaped particles (large aggregates of nanocrystals) | 10–200 μm |
CNC | Hydrolysis with concentrated inorganic acids with mechanical and/or ultrasound treatment | Rigid whiskers, needle-like crystalline particles | Width 3–50 nm Length 100–500 nm (up to several μm for cellulose from algae, tunicate and BC) |
Abbreviations: CNC: cellulose nanocrystals (nanocrystalline cellulose); CMC: cellulose microcrystals (microcrystalline cellulose); CNF: cellulose nanofibers; CMF: cellulose microfibers.