TABLE 1.
pos. | 1 | 2 | ||
---|---|---|---|---|
δ C | δ H (J in Hz) | δ C | δ H (J in Hz) | |
1 | 131.4 | |||
2 | 110.7 | 6.83, d (1.8) | 110.7 | 6.85, d (1.8) |
3 | 147.5 | 147.5 | ||
4 | 145.9 | 145.9 | ||
5 | 115.5 | 6.79, d (8.2) | 115.5 | 6.65, d (8.1) |
6 | 119.4 | 6.70, dd (8.2, 1.8) | 119.8 | 6.73, dd (8.1, 1.8) |
7 | 80.7 | 4.25, d (7.2) | 80.7 | 4.21, d (7.3) |
8 | 44.4 | 2.11, td (7.2, 4.0) | 44.1 | 2.16, m |
9 | 63.4 | 3.80, m, 3.99, dd (11.1, 4.0) | 63.1 | 4.19, m, 4.26, m |
10 | 63.5 | 3.26, m, 3.33, m | 63.5 | 3.22, dd (9.5, 7.0), 3.29, m |
11 | 15.2 | 1.11, t (7.0) | 15.2 | 1.07, t (7.0) |
1′ | 125.5 | 125.5 | ||
2′ | 111.1 | 7.29, d (2.0) | 111.1 | 7.30, d (2.0) |
3′ | 147.9 | 147.9 | ||
4′ | 149.4 | 149.4 | ||
5′ | 115.2 | 6.79, d (8.2) | 115.2 | 6.77, d (8.2) |
6′ | 123.2 | 7.07, dd (8.2, 2.0) | 123.2 | 7.07, dd (8.2, 2.0) |
7′ | 144.9 | 7.48, d (15.9) | 144.9 | 7.51, d (15.9) |
8′ | 114.3 | 6.44, d (15.9) | 114.3 | 6.46, d (15.9) |
9′ | 166.5 | 166.7 | ||
1″ | 128.9 | 128.9 | ||
2″ | 109.4 | 6.94, d (2.0) | 109.4 | 6.89, d (1.9) |
3″ | 147.6 | 147.6 | ||
4″ | 145.8 | 145.8 | ||
5″ | 115.4 | 6.67, d (8.1) | 115.4 | 6.79, d (8.2) |
6″ | 119.0 | 6.74, dd (8.1, 2.0) | 119.0 | 6.71, dd (8.2, 1.9) |
7″ | 131.2 | 6.27, d (15.3) | 131.3 | 6.17, d (15.1) |
8″ | 125.2 | 6.08, dd (15.3, 7.6) | 124.7 | 5.96, dt (15.1, 7.0) |
9″ | 30.8 | 2.30, dt (14.9, 7.6), 2.48, m c | 31.4 | 2.05, dt (14.6, 7.0), 2.14, m |
MeO-3 | 55.5 | 3.74, s | 55.6 | 3.75, s |
MeO-3′ | 55.7 | 3.82, s | 55.7 | 3.81, s |
MeO-3″ | 55.4 | 3.74, s | 55.5 | 3.72, s |
Recorded at 600 MHz (1H) and 150 MHz (13C).
Recorded at 400 MHz (1H) and 100 MHz (13C).
Overlapping with solvent peak.