The results of copolymerization of ethylene with 1-octene using (F-salalen)TiCl₂ in the presence of MAO^a.

Entry	Al/Ti (mol mol−1)	T p (°C)	1-Oct. feed (mol L−1)	Activityb	M w c ×10−6	M w/Mnc	T m d (°C)	ΔHd (J g−1)	X c d (%)	1-Oct. cont.e (mol%)
1	600	50	0	56.5	2.64	2.4	134.6	204.5	69.8	0
2f	600	50	1.2	n.d	—	—	—			—
3	600	30	1.0	35.6	1.89	2.1	125.0	177.3	60.5	0.9
4	600	40	1.0	42.0	1.23	2.2	124.1	141.0	48.1	1.8
5	600	50	1.0	92.3	0.87	2.6	119.4	80.6	27.5	3.1
6	600	70	1.0	141.0	0.22	3.2	120.5	85.3	29.1	2.0
7	600	90	1.0	101.2	0.10	3.9	120.9	136.9	46.7	1.9
8	200	50	1.0	63.5	1.64	1.9	123.5	101.1	34.5	2.0
9	400	50	1.0	87.0	1.24	2.1	123.3	83.8	28.6	2.6
10	800	50	1.0	35.0	0.57	3.4	123.5	101.4	34.6	2.2
11	600	50	0.2	79.8	1.26	2.7	128.7	172.1	58.7	1.2
12	600	50	0.4	127.5	1.00	2.9	124.4	160.6	54.8	1.7
13	600	50	0.8	132.5	0.89	2.6	122.3	92.2	31.5	2.8
14	600	50	2.0	64.0	0.78	2.7	117.9	65.8	22.5	6.4

^aPolymerization conditions: catalyst, 20.0 μmol; ethylene pressure, 15 atm; total volume, 70 mL; reaction time, 30 min.

^b10³ g polymer (mol Ti)⁻¹ h⁻¹.

^cg mol⁻¹, determined by HT-GPC in 1,2,4-TCB versus polystyrene standard.

^dDetermined by DSC at a heating rate of 10 °C min⁻¹ and used the second heating curves.

^e1-Octene incorporation (mol%) estimated by ¹³C NMR spectra.

^f1-Octene homopolymerization, ethylene pressure, 0 atm.