Table 3.
RSD values for the precision of ICP-MS during the determination of Ca, Cd, and Pb in the lowest standard solution (10 mM, 10 μM, and 10 μM, respectively (n = 3 samples)).
| Ca | |||
| Day | Measured concentration (mM) | RSD value (%) | |
| Repeatability | Intermediate precision | ||
|
| |||
| First | 10.3 ± 0.04 | 0.4 | |
| Fourth | 9.35 ± 0.02 | 0.2 | 1.3 |
| Sixth | 10.6 ± 0.01 | 0.090 | |
|
| |||
| Cd | |||
| Day | Measured concentration (μM) | RSD value (%) | |
| Repeatability | Intermediate precision | ||
|
| |||
| First | 9.40 ± 0.05 | 0.5 | |
| Fourth | 9.89 ± 0.08 | 0.8 | 1.0 |
| Sixth | 9.93 ± 0.03 | 0.3 | |
|
| |||
| Pb | |||
| Day | Measured concentration (μM) | RSD value (%) | |
| Repeatability | Intermediate precision | ||
|
| |||
| First | 10.1 ± 0.01 | 0.1 | |
| Fourth | 9.94 ± 0.04 | 0.4 | 0.4 |
| Sixth | 10.2 ± 0.01 | 0.1 | |