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. 2022 Mar 20;42(3):360–366. [Article in Chinese] doi: 10.12122/j.issn.1673-4254.2022.03.07

表 2.

六类白芷挥发油成分组成及相对含量

Volatile constituents and relative content of the 6 specimens of Angelica dahurica (%)

Formula Molecular weight Compounds Classification Chuanbaizhi Hangbaizhi Qibaizhi Yubaizhi Bobaizhi Angelica dahurica
C5H10O 86.07 2-Buten-1 -ol, 3 -methyl- Alcohols 0.292 0.305 2.012 3.498 0.565
C10H18O 154.14 Terpinen-4-ol Alcohols 3.219 0.867
C10H18O 154.14 beta-Fenchylalcohol Alcohols 0.485
C10H22O 158.17 1 -Decanol Alcohols 1.03
C15H26O 222.2 1，6，10-Dodecatrien-3-ol，3, 7，11- trimethyl-, Alcohols 0.42
C13H28O 200.21 n-Tridecan-1-ol Alcohols 0.484 1.214
C15H26O 222.2 Epiglobulol Alcohols 1.474
C15H24O 220.18 Spathulenol Alcohols 2.556 2.139 1.122 1.998 2.884
C15H26O 222.2 Farnesol Alcohols 0.789
C15H26O 222.2 Junipercamphor Alcohols 0.671
C15H24O 220.18 valerenol Alcohols 1.535
C16H34O 242.26 1-Hexadecanol Alcohols 0.385 1.876 2.792
C18H36O 268.28 9-Octadecen-1 -ol，(Z)- Alcohols 0.799 7.053 4.546 0.288 1.715
C16H32O 240.25 11-Hexadecen-1-ol，(Z)- Alcohols 0.18 1.32 0.483
Alcohols 6.874 14.648 11.169 4.636 8.685 4.984
C8H12N2 136.1 Pyrazine，tetramethyl- Nitrogen heterocycles 2.91
Nitrogen heterocycles 2.91
C10H14 134.11 p-Cymene Aromatic hydrocarbons 0.406
C15H22 202.17 (+)-cuparene Aromatic hydrocarbons 0.785 2.386
Aromatic hydrocarbons 0.406 0.785 2.386
C12H8O4 216.04 Xanthotoxin Quinones 0.789
Quinones 0.789
C12H16O3 208.11 trans-isoelemicin Ethers 1.741 2.68
Ethers 1.741 2.68
C8H16O 128.12 Octanal Aldehydes 0.355 0.369 0.446
C5H4O2 96.02 Furfural Aldehydes 0.574
C13H26O 198.2 Tridecanal Aldehydes 1.202
Aldehydes 1.202 0.355 0.369 0.574 0.446
C16H30O2 254.22 Palmitoleic acid Organic acids 3.422
C10H20O2 172.15 n-Decanoic acid Organic acids 1.353
C18H30O2 278.23 GamolenicAcid Organic acids 5.647
C14H28O2 228.21 Tetradecanoicacid Organic acids 3.445 2.093
C15H30O2 242.22 Pentadecanoicacid Organic acids 2.686 2.145
C18H32O2 280.24 9, 12-Octadecadienoicacid(Z，Z)- Organic acids 1.657
C16H32O2 256.24 n-Hexadecanoic acid Organic acids 1.856 7.497 20.472 24.236 1.632
Organic acids 5.301 7.497 24.815 29.827 10.701
C9H18O 142.14 2-Nonanone Ketones 0.308
C11H22O 204.19 2-Undecanone Ketones 0.399
C12H22O 182.17 Cyclododecanone Ketones 0.827
C15H22O 218.17 Aristolone Ketones 1.199 3.921 4.861
C15H22O 218.17 (+)-.alpha.-Cyperone Ketones 3.664 0.37 1.551
Ketones 2.026 7.585 1.077 6.412
C12H24 168.19 Cyclopropane，nonyl- Alkanes 56.337 15.924 42.35 4.592
C12H24 168.19 Cyclododecane Alkanes 23.134 11.133 19.088 24.162 5.148 3.881
C10H16 136.13 alpha.-Phellandrene Olefins 1.471
C10H16 136.13 D-Limonene Olefins 0.393 0.535
C10H16 136.13 Sabinene Olefins 4.676 0.511
C10H16 136.13 trans-.beta.-Ocimene Olefins 3.505
C10H16 136.13 alpha-Terpinene Olefins 0.68 0.854
C15H24 204.19 cis-α-bisabolene Olefins 0.273
C15H24 204.19 Cedrene Olefins 0.934
C15H24 204.19 gamma. 1 -cadinene Olefins 1.184
C15H24 204.19 beta-elemene Olefins 0.135 2.609 1.105 3.651 4.239
C15H24 204.19 beta-Caryophyllene Olefins 0.325 0.735 5.417
C15H24 204.19 Aromandendrene Olefins 0.328 1.185
C15H24 204.19 Alpha.-Humulene Olefins 0.172 0.568 1.376
C15H24 204.19 alpha.-Gurjunene Olefins 0.632
C15H24 204.19 germacreneD Olefins 0.74 1.176 2.394
C15H24 204.19 beta-selinene Olefins 1.229 1.013
C15H24 204.19 alpha.-selinene Olefins 1.842 0.937
C15H24 204.19 bicyclogermacrene Olefins 1.417 1.155 2.725
C15H24 204.19 delta.-Cadinene Olefins 0.266
C15H24 204.19 germacrene A Olefins 5.164 1.737 2.652 4.584
C15H24 204.19 beta.-Maaliene Olefins 2.458 1.232 1.781
C15H24 204.19 beta.-Himachalene Olefins 0.625
C15H24 204.19 Germacrene B Olefins 0.804 4.13 2.978 4.182 13.129
C10H20 140.16 1-Decene Olefins 4.265
C12H24 168.19 1-Dodecene Olefins 0.311
C15H24 204.19 (Z, Z)-.alpha.-Farnesene Olefins 1.713
C14H28 196.22 1 -Tetradecene Olefins 1.887 1.318
C15H24O 220.18 Isoaromadendreneepoxide Olefins 2.373
C10H16 136.13 Cyclooctene, 3-ethenyl- Olefins 0.493
C11H18 150.14 Cyclohexane, 2, 4-diethenyl-1 -methyl- Olefins 2.441 4.926
Olefins 2.013 28.727 6.152 12.847 25.053 42.778
C15H24O 220.18 Caryophylleneoxide Esters 0.63 0.481 3.784
C16H28O2 252.21 Ambrettolide Esters 1.009 1.849
C14H28O2 228.21 lauryl acetate Esters 1.791 0.66 2.904 1.381
C16H28O2 226.19 Oxacyclotetradecan-2-one, 14-methyl- Esters 3.21
C16H32O2 256.24 lauryl acetate Esters 0.173
C15H28O2 240.2 Muskolactone Esters 0.292 7.343 0.524 2.145 2.856 9.84
C21H38O2 322.29 11, 14-Eicosadienoic acid, methyl ester Esters 1.601 2.338
C17H34O2 270.26 Hexadecanoicacid, methyl ester Esters 0.19 1.328 0.657
C18H36O2 284.27 Hexadecanoicacid, ethylester Esters 0.375 3.315 4.221 2.361 5.926
C16H30O2 254.22 Hexadecanolide Esters 2.11 4.54
C20H38O2 310.29 Ethyl Oleate Esters 1.175
C19H34O2 294.26 9, 12-Octadecadienoic acid (Z, Z)-methyl ester Esters 0.136 2.797 1.32 2.552
C20H36O2 308.27 9, 12-Octadecadienoic acid (Z, Z)-, ethylester Esters 0.264 0.797 4.1 1.167 4.041
C16H22O4 278.15 1, 2-Benzenedicarboxylicacid, bis(2- methylpropyl)ester Esters 3.27
C18H30O2 278.23 Methyl-8, 11, 14-heptadecatrienoate Esters 1.184
C16H22O4 278.15 Dibutylphthalate Esters 0.913 6.185 0.975 1.918
Esters 4.134 16.835 25.959 10.487 22.252 22.961
Total 98.995 99.292 95.557 99.623 96.131 97.229