Monoallylation of various anilines using 10 wt% WO3/ZrO2a.
| ||
|---|---|---|
| Products | Yieldsb (%) of N-allyl anilines | Selectivity (mono : di)c (%) |
|
58 | 98 |
|
33 | 97 |
|
43 | 96 |
|
45 | 98 |
|
25 | 96 |
|
30 | —d |
|
29 | 97 |
|
54 | 95 |
|
17 | 94 |
|
29 | —d |
|
63 | —d |
|
29 | —d |
Reaction conditions: 1 (2.0 mmol), aniline (1.0 mmol), WO3/ZrO2 (100 mg), n-octane (0.25 mL), 140 °C, 24 h.
Isolated yield.
Selectivity (mono : di) = ((isolated yield of N-allyl aniline)/[(isolated yield of N-allyl aniline) + (isolated yield of N,N-diallyl aniline)]) × 100 (%).
Small amounts of the other compounds were contaminated.