Skip to main content
. 2022 Apr 19;12(19):11877–11884. doi: 10.1039/d2ra00198e

Monoallylation of various anilines using 10 wt% WO3/ZrO2a.

graphic file with name d2ra00198e-u3.jpg
Products Yieldsb (%) of N-allyl anilines Selectivity (mono : di)c (%)
graphic file with name d2ra00198e-u4.jpg 58 98
graphic file with name d2ra00198e-u5.jpg 33 97
graphic file with name d2ra00198e-u6.jpg 43 96
graphic file with name d2ra00198e-u7.jpg 45 98
graphic file with name d2ra00198e-u8.jpg 25 96
graphic file with name d2ra00198e-u9.jpg 30 d
graphic file with name d2ra00198e-u10.jpg 29 97
graphic file with name d2ra00198e-u11.jpg 54 95
graphic file with name d2ra00198e-u12.jpg 17 94
graphic file with name d2ra00198e-u13.jpg 29 d
graphic file with name d2ra00198e-u14.jpg 63 d
graphic file with name d2ra00198e-u15.jpg 29 d
a

Reaction conditions: 1 (2.0 mmol), aniline (1.0 mmol), WO3/ZrO2 (100 mg), n-octane (0.25 mL), 140 °C, 24 h.

b

Isolated yield.

c

Selectivity (mono : di) = ((isolated yield of N-allyl aniline)/[(isolated yield of N-allyl aniline) + (isolated yield of N,N-diallyl aniline)]) × 100 (%).

d

Small amounts of the other compounds were contaminated.