Table 7.
Correlation coefficients (r) between antioxidant capacity determined by different analytical methods, total phenolics, phenolic acids, carotenoids and tocopherols in the investigated chocolates.
Compound | DPPH | ABTS | CUPRAC | FRAP |
---|---|---|---|---|
TPC | 0.99 * | 0.95 * | 0.95 * | 0.93 * |
Gallic acid | −0.10 | 0.11 | 0.17 | 0.17 |
Protocatechuic acid | 0.50 | 0.49 | 0.56 | 0.52 |
Gentistic acid | −0.19 | −0.01 | 0.05 | 0.05 |
Chlorogenic acid | −0.06 | 0.15 | 0.21 | 0.22 |
p-OH-benzoic acid | 0.56 | 0.35 | 0.35 | 0.31 |
Caffeic acid | 0.49 | 0.37 | 0.42 | 0.38 |
Salicylic acid | −0.04 | 0.16 | 0.23 | 0.23 |
Syringic acid | 0.44 | 0.24 | 0.24 | 0.21 |
Ferulic acid | 0.29 | 0.11 | 0.11 | 0.08 |
m-Coumaric acid | −0.10 | 0.13 | 0.18 | 0.19 |
Sinapic acid | −0.55 | −0.57 | −0.63 | −0.60 |
Vanillic acid | −0.26 | −0.03 | 0.01 | 0.03 |
p-Coumaric acid | 0.52 | 0.33 | 0.35 | 0.31 |
Ellagic acid | 0.52 | 0.32 | 0.33 | 0.29 |
Total phenolic acids | 0.01 | 0.21 | 0.27 | 0.27 |
Luteoxanthin | −0.02 | 0.16 | 0.22 | 0.22 |
Cis-lutein | −0.02 | 0.11 | 0.19 | 0.17 |
Trans-lutein | 0.52 | 0.35 | 0.37 | 0.33 |
Zeaxanthin | 0.44 | 0.24 | 0.25 | 0.21 |
13-cis-β-carotene | 0.42 | 0.23 | 0.23 | 0.19 |
α-carotene | 0.18 | 0.33 | 0.41 | 0.39 |
Trans-β-carotene | 0.47 | 0.27 | 0.27 | 0.24 |
9-cis-β-carotene | 0.49 | 0.30 | 0.31 | 0.27 |
Total carotenoids | 0.50 | 0.33 | 0.35 | 0.31 |
α-tocopherol | 0.27 | 0.09 | 0.04 | 0.03 |
γ-tocopherol | −0.24 | −0.35 | −0.43 | −0.41 |
δ-tocopherol | 0.30 | 0.09 | 0.09 | 0.06 |
Total tocopherols | −0.14 | −0.28 | −0.35 | −0.33 |
* Statistically significant at p ≤ 0.05.